Single‐Atom based Metal–Organic Framework Photocatalysts for Solar‐Fuel Generation

Abstract The growing demand for fossil fuels and subsequent CO₂ emissions prompted a search for alternate sources of energy and a reduction in CO₂. Photocatalysis driven by solar light has been found as a potential research area to tackle both these problems. In this direction, SAC@MOF (Single‐atom loaded MOFs) photocatalysis is an emerging field and a promising technology. The unique properties of single‐atom catalysts (SACs), such as high catalytic activity and selectivity, are leveraged in these systems. Photocatalysis, focusing on the utilization of Metal–Organic Frameworks (MOFs) as platforms for creating single‐atom catalysts (SACs) characterized by metal single‐atoms (SAs) as their active sites, are noted for their unparalleled atomic efficiency, precisely defined active sites, and superior photocatalytic performance. The synergy between MOFs and SAs in photocatalytic systems is meticulously examined, highlighting how they collectively enhance photocatalytic efficiency. This review examines SAC@MOF development and applications in environmental and energy sectors, focusing on synthesis and stabilization methods for SACs on MOFs and also characterization techniques vital for understanding these catalysts. The potential of SAC@MOF in CO₂ Photoreduction and Photocatalytic H₂ evolution is highlighted, emphasizing its role in green energy technologies and advances in materials science and Photocatalysis.