Carbon Yarn‐Ball‐Entangled SiO₂ Anode with Excellent Electrochemical Performance for Lithium‐Ion Batteries

Abstract Various nanoscale SiO₂ and their composites have demonstrated superior electrochemical performance as anodes for lithium‐ion batteries. However, both the battery production and real applications require the integration of nanoscale SiO₂ into micrometer‐sized secondary particles while preserving their excellent stability and conductivity, which remains a great challenge. In this work, a unique carbon yarn‐ball structure is successfully synthesized that entangles nanoscale SiO₂ together to build a micrometer‐sized secondary particle. The hook‐like carbon wires closely adhere to individual SiO₂ nanoparticles, which constitute the basic unit of the yarn‐ball structure. The entangled carbon wires create a network of electron conduction highways for SiO₂, and the yarn‐ball structure provides a resilient 3D matrix that can effectively buffer the anisotropic volume changes of SiO₂ during Li ion insertion/extraction. Under 0.1 A g⁻¹, the carbon yarn‐ball‐entangled SiO₂ can deliver a 1297 mAh g⁻¹ discharge capacity with a small irreversible capacity of 82 mAh g⁻¹. The entangled carbon yarn ball firmly maintains its structural integrity during high‐rate cycling (1 A g⁻¹), which gives rise to a large accessible capacity (709 mAh g⁻¹, 90.7% retention for 500 cycles), superior coulombic efficiency (>99.9%), and excellent structural stability.