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journal article·2024-03Open access

Inorganic‐Organic Nanoarchitectonics: MXene/Covalent Organic Framework Heterostructure for Superior Microextraction

Jingyu Wu, Zhuo Wang, Shuaihua Zhang, Qian Yang, Zhi Li, Xiaohuan Zang, Xiaoxian Zhao, Ningzhao Shang, Nithima Khaorapapong, Xingtao Xu, Yusuke Yamauchi

Small· Volume 20· Issue 10
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Source abstract

Abstract

Abstract One of the difficulties limiting covalent organic frameworks (COFs) from becoming excellent adsorbents is their stacking/aggregation architectures owing to poor morphology/structure control during the synthesis process. Herein, an inorganic‐organic nanoarchitectonics strategy to synthesize the MXene/COF heterostructure (Ti3C2Tx/TAPT‐TFP) is developed by the assembly of β‐ketoenamine‐linked COF on the Ti3C2Tx MXene nanosheets. The as‐prepared Ti3C2Tx/TAPT‐TFP retains the 2D architecture and high adsorption capacity of MXenes as well as large specific surface area and hierarchical porous structure of COFs. As a proof of concept, the potential of Ti3C2Tx/TAPT‐TFP for solid‐phase microextraction (SPME) of trace organochlorine pesticides (OCPs) is investigated. The Ti3C2Tx/TAPT‐TFP based SPME method achieves low limits of detection (0.036–0.126 ng g−1), wide linearity ranges (0.12–20.0 ng g−1), and acceptable repeatabilities for preconcentrating trace OCPs from fruit and vegetable samples. This study offers insights into the potential of constructing COF or MXene‐based heterostructures for the microextraction of environmental pollutants.
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Research context

Nanomaterials

OpenAlex topics: Covalent Organic Framework Applications · Advanced Photocatalysis Techniques · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry Hebei Agricultural University Baoding Hebei 071001 China

School of Chemistry Sun Yat‐sen University Guangzhou Guangdong 510275 China

College of Public Health Hebei University Baoding Hebei 071002 China

Materials Chemistry Research Center Department of Chemistry and Center of Excellence for Innovation in Chemistry Faculty of Science Khon Kaen 40002 Thailand

Marine Science and Technology College Zhejiang Ocean University Zhoushan Zhejiang 316022 China

Department of Materials Process Engineering Graduate School of Engineering Nagoya University Nagoya 464−8603 Japan

Department of Chemical and Biomolecular Engineering Yonsei University 50 Yonsei‐ro, Seodaemun‐gu Seoul 03722 South Korea

Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland Brisbane QLD 4072 Australia

Funding

National Natural Science Foundation of China

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