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journal article·2021-06

Incorporation of Al3+ Sites on Brønsted Acid Metal–Organic Frameworks for Glucose‐to‐Hydroxylmethylfurfural Transformation

Vitsarut Tangsermvit, Taweesak Pila, Bundet Boekfa, Vetiga Somjit, Wantana Klysubun, Jumras Limtrakul, Satoshi Horike, Kanokwan Kongpatpanich

Small· Volume 17· Issue 22
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Source abstract

Abstract

Abstract 5‐hydroxylmethylfurfural (HMF) is a bio‐based chemical that can be prepared from natural abundant glucose by using combined Brønsted–Lewis acid catalysts. In this work, Al3+ catalytic site has been grafted on Brønsted metal–organic frameworks (MOFs) to enhance Brønsted–Lewis acidity of MOF catalysts for a one‐pot glucose‐to‐HMF transformation. The uniform porous structure of zirconium‐based MOFs allows the optimization of both acid strength and density of acid sites in MOF‐based catalysts by incorporating the desired amount of Al3+ catalytic sites at the organic linker. Al3+ sites generated via a post‐synthetic modification act as Lewis acid sites located adjacent to the Brønsted sulfonated sites of MOF structure. The local structure of the Al3+ sites incorporated in MOFs has been elucidated by X‐ray absorption near‐edge structure (XANES) combined with density functional theory (DFT) calculations. The cooperative effect from Brønsted and Lewis acids located in close proximity and the high acid density is demonstrated as an important factor to achieve high yield of HMF.
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Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Catalysis for Biomass Conversion · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering School of Molecular Science and Engineering Vidyasirimedhi Institute of Science and Technology Rayong 21210 Thailand

Department of Chemical and Biomolecular Engineering School of Energy Science and Engineering Vidyasirimedhi Institute of Science and Technology Rayong 21210 Thailand

Faculty of Liberal Arts and Science Kasetsart University Kamphaeng Saen Campus Nakhon Pathom 73140 Thailand

Synchrotron Light Research Institute (Public Organization) Nakhon Ratchasima 30000 Thailand

Institute for Integrated Cell‐Material Science Institute for Advanced Study Kyoto University Yoshida‐Honmachi, Sakyo‐ku Kyoto 606‐8501 Japan

Research Network of NANOTEC‐VISTEC on Nanotechnology for Energy Vidyasirimedhi Institute of Science and Technology Wangchan Rayong 21210 Thailand

Funding

Thailand Research Fund · Office of the Higher Education Commission · National Science and Technology Development Agency · Ministry of Science and Technology

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