journal article·2012-01

Efflorescence control in geopolymer binders based on natural pozzolan

Ebrahim Najafi Kani, Ali Allahverdi, John L. Provis

Cement and Concrete Composites· Volume 34· Issue 1
Publisher page

Abstract

Abstract This paper addresses methods to reduce efflorescence in a geopolymer binder based on a pumice-type natural pozzolanic material from Taftan, Iran. Geopolymer pastes samples are analyzed for compressive strength and efflorescence formation after curing at 95% humidity for 28 days. To reduce the extent of efflorescence, Al-rich mineral admixtures such as metakaolin, ground granulated blast-furnace slag, and three types of calcium aluminate cements are incorporated into the dry binder at a range of concentrations. Hydrothermal curing at elevated temperatures also shows a positive effect in efflorescence reduction. Calcium aluminate cements show the greatest effect in efflorescence reduction, which is attributed to their dissolution in alkaline media releasing high amounts of alumina into the aluminosilicate geopolymer gel. These results confirm that it is possible to develop a more reliable geopolymer binder with improved properties either by adding a suitable amount of active alumina to precursors such as natural pozzolan, or by manipulating the curing conditions to enhance alumina release from less-reactive precursor phases.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Concrete and Cement Materials Research · Magnesium Oxide Properties and Applications · Innovative concrete reinforcement materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Davidovits · 2008
2. Effect of alkali cations on aluminum incorporation in geopolymeric gels10.1021/ie0494216 ↗
3. Geopolymer technology: the current state of the art10.1007/s10853-006-0637-z ↗
4. Geopolymerisation kinetics. 2. Reaction kinetic modelling10.1016/j.ces.2007.01.028 ↗
5. Spatial distribution of pores in fly ash-based inorganic polymer gels visualised by Wood’s metal intrusion10.1016/j.micromeso.2009.05.016 ↗
6. Effects of chemical composition on basic engineering properties of inorganic polymeric binders based on natural pozzolan
7. Investigating the possibility of utilizing pumice-type natural pozzolan in production of geopolymer cement
8. Aluminosilicate polymers – influence of elevated temperatures, efflorescence
9. Effect of fly ash preliminary calcination on the properties of geopolymer10.1016/j.jhazmat.2008.08.065 ↗
10. Influence of sodium carbonate addition on the thermal reactivity of tungsten mine waste mud based binders10.1016/j.conbuildmat.2009.08.018 ↗
11. Effect of silicate modulus and metakaolin incorporation on the carbonation of alkali silicate-activated slags10.1016/j.cemconres.2010.02.003 ↗
12. Alkali activation of fly ashes. Part 1: effect of curing conditions on the carbonation of the reaction products10.1016/j.fuel.2005.03.030 ↗
13. Pore solution composition and alkali diffusion in inorganic polymer cement10.1016/j.cemconres.2010.04.008 ↗
14. Influence of alkali ions in the activator on the performance of alkali-activated mortars
15. High temperature properties of fly ash-based geopolymers
16. Metal ions as probes for characterization of geopolymer materials10.1111/j.1551-2916.2008.02577.x ↗
17. 39K NMR of free potassium in geopolymers10.1021/ie060838g ↗
18. Effect of curing temperature on the development of hard structure of metakaolin-based geopolymer10.1016/j.conbuildmat.2009.12.023 ↗
19. Preparation and thermal properties of fire resistant metakaolin-based geopolymer-type coatings10.1016/j.jnoncrysol.2010.09.063 ↗
20. Carbonate mineral addition to metakaolin-based geopolymers10.1016/j.cemconcomp.2008.07.004 ↗
21. Geopolymers from Algerian metakaolin. Influence of secondary minerals10.1016/j.clay.2008.11.001 ↗
22. The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers10.1016/j.colsurfa.2006.05.044 ↗
23. Preparation and characterisation of fly ash based geopolymer mortars10.1016/j.conbuildmat.2010.04.012 ↗
24. Compressive strength and degree of reaction of biomass- and fly ash-based geopolymer10.1016/j.conbuildmat.2009.09.002 ↗
25. Workability and strength of coarse high calcium fly ash geopolymer10.1016/j.cemconcomp.2006.11.002 ↗
26. Environmental, physical and structural characterisation of geopolymer matrixes synthesised from coal co-combustion fly ashes10.1016/j.jhazmat.2007.10.008 ↗
27. The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer10.1016/j.chemosphere.2010.02.018 ↗
28. Effect of mechanical activation of fly ash on the properties of geopolymer cured at ambient temperature10.1016/j.jmatprotec.2009.03.016 ↗
29. Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes10.1016/j.jhazmat.2008.12.121 ↗
30. Compressive strength and microstructural characteristics of class C fly ash geopolymer10.1016/j.cemconcomp.2009.11.003 ↗
31. Coal fly ash as raw material for the manufacture of geopolymer-based products10.1016/j.wasman.2007.02.001 ↗
32. Factors affecting the suitability of fly ash as source material for geopolymers10.1016/j.fuel.2009.09.012 ↗
33. Effects of curing time and temperature on strength development of inorganic polymeric binders based on natural pozzolan10.1007/s10853-009-3411-1 ↗
34. Taftan pozzolan-based geopolymer cement
35. Geopolymer cement from Sirjan pozzolan
36. Understanding the relationship between geopolymer composition, microstructure and mechanical properties10.1016/j.colsurfa.2005.06.060 ↗
37. Effects of blast-furnace slag on natural pozzolan-based geopolymer cement
38. Strength and microstructural development
39. Study of hydration mechanisms in the high alumina cement–sodium silicate system10.1016/S0008-8846(96)85017-4 ↗
40. The effect of alumina release rate on the mechanism of geopolymer gel formation10.1021/cm101151n ↗
41. Attenuated total reflectance Fourier transform infrared analysis of fly ash geopolymer gel aging10.1021/la700713g ↗
42. Mid-infrared spectroscopic studies of alkali-activated fly ash structure10.1016/j.micromeso.2005.05.057 ↗