Dual‐Defect Engineering of Bidirectional Catalyst for High‐Performing Lithium‐Sulfur Batteries

Abstract Practical applications of lithium‐sulfur (Li‐S) batteries have been hindered by sluggish reaction kinetics and severe capacity decay during charge‐discharge cycling due to the notorious shuttle effect of polysulfide and the unfavored deposition and dissolution of Li₂S. Herein, to address these issues, a double‐defect engineering strategy is developed for preparing Co‐doped FeP catalyst containing P vacancies on MXene, which effectively improves the bidirectional redox of Li₂S. Mechanism analysis indicates that P vacancy accelerates Li₂S nucleation via increased unsaturated sites, and Co doping generates local electric field to reduce the reaction energy barrier and accelerate Li₂S dissolution. MXene provides highly conductive channels for electron transport, and effectively captures polysulfide. The double‐defect catalyst enables an impressive reversible specific capacity of 1297.9 mAh g⁻¹ at 0.2 C, and excellent rate capability of 726.5 mAh g⁻¹ at 4 C. Remarkably, it demonstrates excellent cycling stability with capacity retention of 533.3 mAh g⁻¹ after 500 cycles at 2 C. The results can unlock the double‐defect engineering of vacancy induction and heteroatomic doping towards practical Li‐S batteries.