Recent Advances and Perspectives of Battery-Type Anode Materials for Potassium Ion Storage

Potassium ion energy storage devices are competitive candidates for grid-scale energy storage applications owing to the abundancy and cost-effectiveness of potassium (K) resources, the low standard redox potential of K/K⁺, and the high ionic conductivity in K-salt-containing electrolytes. However, the sluggish reaction dynamics and poor structural instability of battery-type anodes caused by the insertion/extraction of large K⁺ ions inhibit the full potential of K ion energy storage systems. Extensive efforts have been devoted to the exploration of promising anode materials. This Review begins with a brief introduction of the operation principles and performance indicators of typical K ion energy storage systems and significant advances in different types of battery-type anode materials, including intercalation-, mixed surface-capacitive-/intercalation-, conversion-, alloy-, mixed conversion-/alloy-, and organic-type materials. Subsequently, host-guest relationships are discussed in correlation with the electrochemical properties, underlying mechanisms, and critical issues faced by each type of anode material concerning their implementation in K ion energy storage systems. Several promising optimization strategies to improve the K⁺ storage performance are highlighted. Finally, perspectives on future trends are provided, which are aimed at accelerating the development of K ion energy storage systems.