A Multidirectionally Thermoconductive Phase Change Material Enables High and Durable Electricity via Real-Environment Solar–Thermal–Electric Conversion

A solar thermoelectric generator (STEG) that generates electricity from sunlight is expected to be a promising technology for harvesting and conversion of clean solar energy. The integration of a phase-change material (PCM) with the STEG even more enables engines to durably generate power in spite of solar radiation flux. However, its photothermal conversion and output electricity is still limited (<15 W/m2) by the PCM’s deficient thermal management performance, i.e., restricted thermal conductivity and nonuniform heat-transfer behavior under concentrated sunlight radiation. In this study, a biomimetic phase-change composite, with centrosymmetric and a multidirectionally aligned boron nitride network embedded in polyethylene glycol, is tailored for the STEG via a radial ice-template assembly and infiltration strategy, which behaves in a highly and multidirectionally thermoconductive way and enables a rapid transfer of heat flux and uniform temperature distribution with respect to even a spot-like heat source. As a consequence, a powerful STEG is tactfully designed via the integration of this high-thermal-management characteristic and maximum collection of solar beams, for durable and real-environment solar–thermal–electric conversion, with its photothermal energy conversion efficiency of up to 85.1% and a high peak power density of 40.28 W/m2.