journal article·2012-06-26

Incorporation of Manganese Dioxide within Ultraporous Activated Graphene for High-Performance Electrochemical Capacitors

Xin Zhao, Lili Zhang, Shanthi Murali, Meryl D. Stoller, Qinghua Zhang, Yanwu Zhu, Rodney S. Ruoff

ACS Nano· Volume 6· Issue 6
Publisher page

Abstract

Manganese dioxide (MnO(2)) particles 2-3 nm in size were deposited onto a porous "activated microwave expanded graphite oxide" (aMEGO) carbon scaffold via a self-controlled redox process. Symmetric electrochemical capacitors were fabricated that yielded a specific capacitance of 256 F/g (volumetric: 640 F/cm(3)) and a capacitance retention of 87.7% after 1000 cycles in 1 M H(2)SO(4); when normalized to MnO(2), the specific capacitance was 850 F/g. Asymmetric electrochemical capacitors were also fabricated with aMEGO/MnO(2) as the positive electrode and aMEGO as the negative electrode and had a power density of 32.3 kW/kg (for an energy density of 20.8 Wh/kg), an energy density of 24.3 Wh/kg (for a power density of 24.5 kW/kg), and a capacitance retention of 80.5% over 5000 cycles.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical Engineering and the Materials Science and Engineering Program, The University of Texas at Austin, One University Station C2200, Austin, Texas 78712, United States

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, People’s Republic of China

Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230036, People’s Republic of China

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