journal article·2009-10-27

Electron Energy-Loss Spectroscopy (EELS) of Surface Plasmons in Single Silver Nanoparticles and Dimers: Influence of Beam Damage and Mapping of Dark Modes

Ai Leen Koh, Kui Bao, Imran Khan, W. Ewen Smith, Gerald Kothleitner, Peter Nordlander, Stefan A. Maier, David W. McComb

ACS Nano· Volume 3· Issue 10
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Abstract

We demonstrate the use of a scanning transmission electron microscope (STEM) equipped with a monochromator and an electron energy loss (EEL) spectrometer as a powerful tool to study localized surface plasmons in metallic nanoparticles. We find that plasmon modes can be influenced by changes in nanostructure geometry and electron beam damage and show that it is possible to delineate the two effects through optimization of specimen preparation techniques and acquisition parameters. The results from the experimental mapping of bright and dark plasmon energies are in excellent agreement with the results from theoretical modeling.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Plasmonic and Surface Plasmon Research · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials, Imperial College London, London SW7 2AZ, United Kingdom

Laboratory for Nanophotonics and Department of Physics and Astronomy, Rice University, Houston, Texas 77005-1892

Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, United Kingdom

FELMI, Graz University of Technology, Austria

Department of Physics, Imperial College London, London SW7 2AZ, United Kingdom

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