journal article·2020-12-22Open access

Challenges in Plasmonic Catalysis

Emiliano Cortés, Lucas V. Besteiro, Alessandro Alabastri, Andrea Baldi, Giulia Tagliabue, Angela Demetriadou, Prineha Narang

ACS Nano· Volume 14· Issue 12

Abstract

The use of nanoplasmonics to control light and heat close to the thermodynamic limit enables exciting opportunities in the field of plasmonic catalysis. The decay of plasmonic excitations creates highly nonequilibrium distributions of hot carriers that can initiate or catalyze reactions through both thermal and nonthermal pathways. In this Perspective, we present the current understanding in the field of plasmonic catalysis, capturing vibrant debates in the literature, and discuss future avenues of exploration to overcome critical bottlenecks. Our Perspective spans first-principles theory and computation of correlated and far-from-equilibrium light-matter interactions, synthesis of new nanoplasmonic hybrids, and new steady-state and ultrafast spectroscopic probes of interactions in plasmonic catalysis, recognizing the key contributions of each discipline in realizing the promise of plasmonic catalysis. We conclude with our vision for fundamental and technological advances in the field of plasmon-driven chemical reactions in the coming years.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chair in Hybrid Nanosystems, Nanoinstitute Munich, Faculty of Physics, Ludwig-Maximilians-Universität München, 80539 München, Germany

CINBIO, Universidade de Vigo, 36310 Vigo, Spain

Department of Electrical and Computer Engineering, Rice University, 6100 Main Street MS-378, Houston, Texas 77005, United States

DIFFER - Dutch Institute for Fundamental Energy Research, De Zaale 20, 5612 AJ Eindhoven, The Netherlands

Department of Physics and Astronomy, Vrije Universiteit Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands

Laboratory of Nanoscience for Energy Technologies (LNET), EPFL, 1015 Lausanne, Switzerland

School of Physics and Astronomy, University of Birmingham, Birmingham B15 2TT, United Kingdom

John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, United States

Funding

H2020 European Research Council

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