journal article·2012-11-27

Selective Molecular Transport through Intrinsic Defects in a Single Layer of CVD Graphene

Sean C. O’Hern, Cameron A. Stewart, Michael S. H. Boutilier, Juan-Carlos Idrobo, Sreekar Bhaviripudi, Sarit K. Das, Jing Kong, Tahar Laoui, Muataz Atieh, Rohit Karnik

ACS Nano· Volume 6· Issue 11
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Abstract

We report graphene composite membranes with nominal areas more than 25 mm(2) fabricated by transfer of a single layer of CVD graphene onto a porous polycarbonate substrate. A combination of pressure-driven and diffusive transport measurements provides evidence of size-selective transport of molecules through the membrane, which is attributed to the low-frequency occurrence of intrinsic 1-15 nm diameter pores in the CVD graphene. Our results present the first step toward the realization of practical membranes that use graphene as the selective material.
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Research context

OpenAlex topics: Graphene research and applications · Nanopore and Nanochannel Transport Studies · Membrane Separation Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States

Department of Mechanical Engineering, Indian Institute of Technology Madras, Chennai, India

Departments of Mechanical and Chemical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia

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