journal article·2013-03-26

Lithium Superionic Sulfide Cathode for All-Solid Lithium–Sulfur Batteries

Zhan Lin, Zengcai Liu, Nancy J. Dudney, Chengdu Liang

ACS Nano· Volume 7· Issue 3
Publisher page

Abstract

This work presents a facile synthesis approach for core-shell structured Li2S nanoparticles with Li2S as the core and Li3PS4 as the shell. This material functions as lithium superionic sulfide (LSS) cathode for long-lasting, energy-efficient lithium-sulfur (Li-S) batteries. The LSS has an ionic conductivity of 10(-7) S cm(-1) at 25 °C, which is 6 orders of magnitude higher than that of bulk Li2S (∼10(-13) S cm(-1)). The high lithium-ion conductivity of LSS imparts an excellent cycling performance to all-solid Li-S batteries, which also promises safe cycling of high-energy batteries with metallic lithium anodes.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

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Affiliations

Materials Science and Technology Division and ‡Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6124, United States

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