journal article·2020-09-22

Mussel Inspired Highly Aligned Ti3C2Tx MXene Film with Synergistic Enhancement of Mechanical Strength and Ambient Stability

Gang San Lee, Taeyeong Yun, Hyerim Kim, In Ho Kim, Jungwoo Choi, Sun Hwa Lee, Ho Jin Lee, Ho Seong Hwang, Jin Goo Kim, Dae-won Kim, Hyuck Mo Lee, Chong Min Koo, Sang Ouk Kim

ACS Nano· Volume 14· Issue 9
Publisher page

Abstract

Two-dimensional (2D) MXene has shown enormous potential in scientific fields, including energy storage and electromagnetic interference (EMI) shielding. Unfortunately, MXene-based material structures generally suffer from mechanical fragility and vulnerability to oxidation. Herein, mussel-inspired dopamine successfully addresses those weaknesses by improving interflake interaction and ordering in MXene assembled films. Dopamine undergoes in situ polymerization and binding at MXene flake surfaces by spontaneous interfacial charge transfer, yielding an ultrathin adhesive layer. Resultant nanocomposites with highly aligned tight layer structures achieve approximately seven times enhanced tensile strength with a simultaneous increase of elongation. Ambient stability of MXene films is also greatly improved by the effective screening of oxygen and moisture. Interestingly, angstrom thick polydopamine further promotes the innate high electrical conductivity and excellent EMI shielding properties of MXene films. This synergistic concurrent enhancement of physical properties proposes MXene/polydopamine hybrids as a general platform for MXene based reliable applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: MXene and MAX Phase Materials · Electromagnetic wave absorption materials · Energy Harvesting in Wireless Networks

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Creative Research Initiative Center for Multi-dimensional Directed Nanoscale Assembly, Department of Materials Science and Engineering, KAIST Institute for Nanocentury, KAIST, Daejeon 34141, Republic of Korea

Materials Architecturing Research Centre, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea

KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 02841, Republic of Korea

Department of Materials Science and Engineering, KAIST, Daejeon 34141, Republic of Korea

Center for Multidimensional Carbon Materials (CMCM), Institute for Basic Science (IBS), Ulsan 44919, Republic of Korea

Division of Nano & Information Technology, KIST School, Korea University of Science and Technology, Seoul 02792, Republic of Korea

Funding

National Research Foundation of Korea · Institute for Basic Science · Korea Institute of Science and Technology · Ministry of Land, Infrastructure and Transport

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