A Double-Functional Additive Containing Nucleophilic Groups for High-Performance Zn-Ion Batteries
Source abstract
Abstract
Aqueous zinc-ion batteries (AZIBs) have attracted attention for their low cost and environmental friendliness. Unfortunately, commercialization has been hampered by several problems with dendrite growth and side reactions. Herein, we select sodium tartrate (TA-Na) as a dual-functional electrolyte additive to enhance the reversibility of AZIBs. The tartrate anions are preferentially adsorbed on the Zn surface, and then the highly nucleophilic carboxylate will coordinate with Zn 2+ to promote the desolvation of [Zn(H 2 O) 6 ] 2+, leading to uniform Zn deposition on the beneficial (002) plane and inhibiting side reactions and dendrite growth. Consequently, the Zn|Zn cells show a long-term cycling stability of over 1500 cycles at 0.5 mA cm –2 . Moreover, the Ta-Na additive improves the performance of Zn||MnO 2 full cells, evidenced by a cycling life of 1000 cycles at 1 A g –1 under practical conditions with a limited Zn anode (negative/positive capacity ratio of 10/1) and controlled electrolyte (electrolyte/capacity ratio of 20 μL mAh –1 ).
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institutes of Physical Science and Information Technology, Leibniz Joint Research Center of Materials Sciences, Engineering Laboratory of High-Performance Waterborne Polymer Materials of Anhui Province, Anhui Graphene Engineering Laboratory, Key Laboratory of Structure and Functional Regulation of Hybrid Material (Ministry of Education), Anhui University, Hefei 230601, People’s Republic of China
School of Chemical Engineering & Advanced Materials, The University of Adelaide, Adelaide 5005, Australia
Institute for Solid State Physics Laboratory of Nano and Quantum Engineering (LNQE), Leibniz University Hannover, Appelstrasse 2, 30167 Hannover, Germany
Funding
National Natural Science Foundation of China · Natural Science Foundation of Anhui Province · Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, South China University of Technology · Anhui Province · Natural Science Research Projects of Universities in Anhui Province
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