journal article·2011-12-27Open access

Stretching and Breaking of Ultrathin MoS2

Simone Bertolazzi, Jacopo Brivio, Andras Kis

ACS Nano· Volume 5· Issue 12

Abstract

We report on measurements of the stiffness and breaking strength of monolayer MoS(2), a new semiconducting analogue of graphene. Single and bilayer MoS(2) is exfoliated from bulk and transferred to a substrate containing an array of microfabricated circular holes. The resulting suspended, free-standing membranes are deformed and eventually broken using an atomic force microscope. We find that the in-plane stiffness of monolayer MoS(2) is 180 ± 60 Nm(-1), corresponding to an effective Young's modulus of 270 ± 100 GPa, which is comparable to that of steel. Breaking occurs at an effective strain between 6 and 11% with the average breaking strength of 15 ± 3 Nm(-1) (23 GPa). The strength of strongest monolayer membranes is 11% of its Young's modulus, corresponding to the upper theoretical limit which indicates that the material can be highly crystalline and almost defect-free. Our results show that monolayer MoS(2) could be suitable for a variety of applications such as reinforcing elements in composites and for fabrication of flexible electronic devices.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Electrical Engineering Institute, Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.

References (41)

Show source-provided references
1. Novoselov K. S. · Science · 2004 · 306 · 66610.1126/science.1102896 ↗
2. Frindt R. F. · J. Appl. Phys. · 1966 · 37 · 192810.1063/1.1708627 ↗
3. Novoselov K. S. · Proc. Natl. Acad. Sci. U.S.A. · 2005 · 102 · 1045110.1073/pnas.0502848102 ↗
4. Novoselov K. S. · Nature · 2005 · 438 · 19710.1038/nature04233 ↗
5. Zhang Y. · Nature · 2005 · 438 · 20110.1038/nature04235 ↗
6. Du X. · Nature · 2009 · 462 · 19210.1038/nature08522 ↗
7. Joensen P. · Mater. Res. Bull. · 1986 · 21 · 45710.1016/0025-5408(86)90011-5 ↗
8. Schumacher A. · Surf. Sci. Lett. · 1993 · 289 · L595
9. Coleman J. N. · Science · 2011 · 331 · 56810.1126/science.1194975 ↗
10. Radisavljevic B. · Nat. Nanotechnol. · 2011 · 6 · 14710.1038/nnano.2010.279 ↗
11. Kam K. K. · J. Phys. Chem. · 1982 · 86 · 46310.1021/j100393a010 ↗
12. Lebegue S. · Phys. Rev. B · 2009 · 79 · 11540910.1103/PhysRevB.79.115409 ↗
13. Splendiani A. · Nano Lett. · 2010 · 10 · 127110.1021/nl903868w ↗
14. Mak K. F. · Phys. Rev. Lett. · 2010 · 105 · 13680510.1103/PhysRevLett.105.136805 ↗
15. Kuc A. · Phys. Rev. B · 2011 · 83 · 24521310.1103/PhysRevB.83.245213 ↗
16. Tenne R. · Nature · 1992 · 360 · 44410.1038/360444a0 ↗
17. Tenne R. · Chem. Mater. · 1998 · 10 · 322510.1021/cm9802189 ↗
18. Kaplan-Ashiri I. · J. Mater. Res. · 2004 · 19 · 45410.1557/jmr.2004.19.2.454 ↗
19. Kaplan-Ashiri I. · Proc. Natl. Acad. Sci. U.S.A. · 2006 · 103 · 52310.1073/pnas.0505640103 ↗
20. Kis A. · Adv. Mater. · 2003 · 15 · 73310.1002/adma.200304549 ↗
21. Griffith A. · Philos. Trans. R Soc. · 1920 · 221 · 163
22. Frank I. W. · J. Vac. Sci. Technol., B · 2007 · 25 · 255810.1116/1.2789446 ↗
23. Poot M. · Appl. Phys. Lett. · 2008 · 92 · 06311110.1063/1.2857472 ↗
24. Lee C. · Science · 2008 · 321 · 38510.1126/science.1157996 ↗
25. Mohiuddin T. M. G. · Phys. Rev. B · 2009 · 79 · 20543310.1103/PhysRevB.79.205433 ↗
26. Tsoukleri G. · Small · 2009 · 5 · 239710.1002/smll.200900802 ↗
27. Dean C. R. · Nat. Phys. · 2011 · 7 · 69310.1038/nphys2007 ↗
28. Benameur M. M. · Nanotechnology · 2011 · 22 · 12570610.1088/0957-4484/22/12/125706 ↗
29. Weisenhorn A. L. · Appl. Phys. Lett. · 1989 · 54 · 265110.1063/1.101024 ↗
30. Bunch J. S. · Nano Lett. · 2008 · 8 · 245810.1021/nl801457b ↗
31. Nardelli M. B. · Phys. Rev. Lett. · 1998 · 81 · 465610.1103/PhysRevLett.81.4656 ↗
32. Komaragiri U. · J. Appl. Mech. · 2005 · 72 · 20310.1115/1.1827246 ↗
33. Schwerin E. · Z. Tech. Phys. · 1929 · 12 · 651
34. Feldman J. L. · J. Phys. Chem. Solids · 1976 · 37 · 114110.1016/0022-3697(76)90143-8 ↗
35. Gere, J. M.; Timoshenko, S. P.,Mechanics of Materials,3rd ed.PWS-Kent:Boston, MA, 1984; p690.
36. Bhatia N. M. · Int. J. Non-Linear Mech. · 1968 · 3 · 30710.1016/0020-7462(68)90004-8 ↗
37. Kim D.-H. · Science · 2008 · 320 · 50710.1126/science.1154367 ↗
38. Hutter J. L. · Rev. Sci. Instrum. · 1993 · 64 · 186810.1063/1.1143970 ↗
39. Shinno H. · J. Nucl. Mater. · 1988 · 155 · 29010.1016/0022-3115(88)90256-5 ↗
40. Armani, D.; Liu, C.; Aluru, N.InRe-Configurable Fluid Circuits by Pdms Elastomer Micromachining, Micro Electro Mechanical Systems, 1999. MEMS ’99; 12th IEEE International Conference, 17–21 Jan, 1999; pp222–227.10.1109/MEMSYS.1999.746817 ↗
41. Yu M.-F. · Science · 2000 · 287 · 63710.1126/science.287.5453.637 ↗