journal article·2024-09-02

Colloid-Milling Enforcing Nucleation–Growth Separation for Scaling-Up Synthesis of Nanosized Metal–Organic Frameworks

Jiahui Xu, Lixi Chen, Jia Lei, Guangkuo Wei, Juanhao Qiu, Xueyu Wang, Tingfeng Sun, Jian Xie, Jueqiong Wang, Junchang Chen, Yu Gong, Yufei Shen, Duo Zhang, Shuao Wang

ACS Materials Letters· Volume 6· Issue 9
Publisher page

Abstract

Nanosized metal–organic frameworks (nano-MOFs) have shown significant potential across diverse fields, while the challenge of achieving energy- and time-efficient scaling-up synthesis hampers their practical applications. This work presents a cost-effective colloid-milling method that enforces nucleation–growth separation during crystallization for the scalable synthesis of nano-MOFs under ambient conditions. Compared to the static method, the colloid-milling method not only greatly improves the production efficiency by 2 orders of magnitude but also produces smaller nano-MOFs with narrower size distribution that exhibit higher catalytic activity than the larger-sized ones. This work offers a promising option for the large-scale production of nano-MOFs.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Enhanced Oil Recovery Techniques · Dendrimers and Hyperbranched Polymers

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China

School of Life and Environmental Sciences, Shaoxing University, Shaoxing 312000, China

Funding

Soochow University · Jiangsu Planned Projects for Postdoctoral Research Funds · National Key Research and Development Program of China · Western University · China Postdoctoral Science Foundation · Natural Science Foundation of Jiangsu Province · National Natural Science Foundation of China · New Cornerstone Science Foundation · China-Portugal Joint Laboratory of Cultural Heritage Conservation Science

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