journal article·2025-06-02

Three-Dimensional Printable Triple-Bonded Polymer Nanoparticles for Invisible Information Encryption and Robust Anti-Counterfeiting

Wei Zhu, Yuchen Tang, Shun Hu, Wenjing Xu, Dong Yu, Jun Cao, Tingjuan Gao, Aiguo Shen

ACS Materials Letters· Volume 7· Issue 6
Publisher page

Abstract

In the evolving landscape of information encryption technologies, the integration of optical materials into three-dimensional (3D) codes has emerged as a promising solution. However, current approaches were limited by coding capacity, detective permeability, and a complicated preparation process. Addressing this gap, we present an approach involving the development of 3D embedded, invisible Raman codes with chemical vibrations employing 3D-printable triple-bonded nanoparticles. These colorless triple-bonded nanoparticles, characterized by the distinct and stable spectral features of spontaneous Raman scattering, ensure high transparency, durability, and coding capacity. By embedding multiple, visually undetectable Raman-based QR codes within the internal structure of 3D printed objects, rather than using visible measures on 2D surfaces, our multilayered encryption system significantly enhances the information security by invalidating single-layer decoding attempts and requiring the combination of multiple layers to decrypt the embedded information. This innovative approach offers superior security and robustness in information security.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Memory and Neural Computing · Luminescence and Fluorescent Materials · Physical Unclonable Functions (PUFs) and Hardware Security

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Bioengineering and Health

Wuhan Textile University

Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry

Central China Normal University

Funding

Natural Science Foundation of Hubei Province · National Natural Science Foundation of China

References (50)

Show source-provided references
1. 10.1126/science.abc424610.1126/science.abc4246 ↗
2. 10.1002/adma.20120148610.1002/adma.201201486 ↗
3. 10.1002/adma.20230364110.1002/adma.202303641 ↗
4. 10.1038/355192a010.1038/355192a0 ↗
5. 10.1038/nnano.2017.17310.1038/nnano.2017.173 ↗
6. 10.1038/nrurol.2012.14810.1038/nrurol.2012.148 ↗
7. 10.1002/anie.20170212010.1002/anie.201702120 ↗
8. 10.1038/s41467-019-10406-710.1038/s41467-019-10406-7 ↗
9. 10.1002/adfm.20140029810.1002/adfm.201400298 ↗
10. 10.1021/jacs.0c0550610.1021/jacs.0c05506 ↗
11. 10.1002/ange.20230884810.1002/ange.202308848 ↗
12. 10.1016/j.mtcomm.2023.10650810.1016/j.mtcomm.2023.106508 ↗
13. 10.1038/s41467-019-14066-510.1038/s41467-019-14066-5 ↗
14. 10.1038/s41570-017-003110.1038/s41570-017-0031 ↗
15. 10.1126/sciadv.adf197810.1126/sciadv.adf1978 ↗
16. 10.1002/adma.20230061510.1002/adma.202300615 ↗
17. 10.1002/anie.20230041710.1002/anie.202300417 ↗
18. 10.1038/s41377-022-00813-910.1038/s41377-022-00813-9 ↗
19. 10.1126/sciadv.abg398910.1126/sciadv.abg3989 ↗
20. 10.1038/s41467-019-14070-910.1038/s41467-019-14070-9 ↗
21. 10.1021/acs.nanolett.2c0144310.1021/acs.nanolett.2c01443 ↗
22. 10.1002/admi.20220020110.1002/admi.202200201 ↗
23. 10.1039/C9SC05133C10.1039/C9SC05133C ↗
24. 10.1002/anie.20210613610.1002/anie.202106136 ↗
25. 10.1038/nmeth.457810.1038/nmeth.4578 ↗
26. 10.1038/nature2205110.1038/nature22051 ↗
27. 10.34133/research.013610.34133/research.0136 ↗
28. 10.1002/adma.20237034410.1002/adma.202370344 ↗
29. 10.1002/adfm.20211327410.1002/adfm.202113274 ↗
30. 10.1126/sciadv.aav579010.1126/sciadv.aav5790 ↗
31. 10.1039/D1TC05938F10.1039/D1TC05938F ↗
32. 10.1021/acs.nanolett.1c0126110.1021/acs.nanolett.1c01261 ↗
33. 10.1038/s41586-024-07399-910.1038/s41586-024-07399-9 ↗
34. 10.1038/s41586-024-07061-410.1038/s41586-024-07061-4 ↗
35. 10.1038/nature2100310.1038/nature21003 ↗
36. 10.1126/science.add838210.1126/science.add8382 ↗
37. 10.1002/adma.20220126210.1002/adma.202201262 ↗
38. 10.1039/C9CS00757A10.1039/C9CS00757A ↗
39. 10.1038/s41467-022-31978-x10.1038/s41467-022-31978-x ↗
40. 10.1002/adfm.20230376510.1002/adfm.202303765 ↗
41. 10.1038/s41928-022-00788-w10.1038/s41928-022-00788-w ↗
42. 10.1038/s41467-024-45428-310.1038/s41467-024-45428-3 ↗
43. 10.1002/advs.20230587610.1002/advs.202305876 ↗
44. 10.1038/s41467-023-38178-110.1038/s41467-023-38178-1 ↗
45. 10.1002/adma.20210541810.1002/adma.202105418 ↗
46. 10.1038/s41467-021-24057-010.1038/s41467-021-24057-0 ↗
47. 10.1038/s41565-023-01405-310.1038/s41565-023-01405-3 ↗
48. 10.1038/s41467-021-27278-510.1038/s41467-021-27278-5 ↗
49. 10.1038/s41467-019-10406-710.1038/s41467-019-10406-7 ↗
50. 10.1038/s41467-024-47479-y10.1038/s41467-024-47479-y ↗