DataVXACS Materials LettersPaper
journal article·2025-01-06

In Situ Reversible Formation Proton-Shuttling Covalent Organic Framework Catalyst for Promoting Hydration of Nitriles

Wenying Ai, Yuan Liu, Youshi Lan, Jiawei Zou, Kun Cui, Jialei Du, Pengyu Li, Yu Yang, Jianbin Gu, Tao Shen, Mingli Jiao

ACS Materials Letters· Volume 7· Issue 1
Publisher page
Source abstract

Abstract

Proton transport via a dynamic chemistry method is an essential pathway in both biology and chemistry. In chemical catalysis, proton-shuttling catalysts were developed by mimicking the proton-transport processes in biological systems. However, YH (Y = O, N, S, etc.) units are typically essential for enabling proton transport in these catalysts. Herein, we present a novel strategy for constructing in situ reversible proton-shuttling covalent organic framework catalysts, avoiding the need for Y–H functional groups. Specifically, we demonstrate that the 2D bis(imino)pyridine Cu-bipy-COF material could transform to a water proton-shuttling catalyst by using the reversible interconversion between imine and hemiamine. This catalyst could effectively catalyze the hydration of benzonitrile in neat water without the use of a toxic organic solvent.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Electronics and Energy Storage

Zhongyuan University of Technology

Department of Radiochemistry, China Institute of Atomic Energy, No.1 Sanqiang Road, Fangshan District, Beijing 102413, P. R. China

Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering

Zhangjiang Institute for Advanced Study, Shanghai Jiao Tong University

Institute for Advanced Interdisciplinary Research (iAIR), Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong

University of Jinan

Funding

Key Scientific Research Project of Colleges and Universities in Henan Province · Zhongyuan University of Technology · Science and Technology Innovation Talents in Universities of Henan Province · Science and Technology Department of Henan Province · National Natural Science Foundation of China

References (59)

Show source-provided references
1. 10.1038/nchem.254710.1038/nchem.2547 ↗
2. 10.1126/science.109170810.1126/science.1091708 ↗
3. 10.1038/1667210.1038/16672 ↗
4. 10.1038/3984310.1038/39843 ↗
5. 10.1038/nmat252610.1038/nmat2526 ↗
6. 10.1016/j.bbabio.2006.07.00410.1016/j.bbabio.2006.07.004 ↗
7. 10.1021/jacs.6b0646110.1021/jacs.6b06461 ↗
8. 10.1002/anie.20231211310.1002/anie.202312113 ↗
9. 10.1002/anie.20221297610.1002/anie.202212976 ↗
10. 10.1021/jacs.0c0453210.1021/jacs.0c04532 ↗
11. 10.1002/anie.20140023610.1002/anie.201400236 ↗
12. 10.1039/C7CC09549J10.1039/C7CC09549J ↗
13. 10.1002/ange.20240488610.1002/ange.202404886 ↗
14. 10.1021/acs.chemrev.9b0055010.1021/acs.chemrev.9b00550 ↗
15. 10.1021/jacs.8b1033410.1021/jacs.8b10334 ↗
16. 10.1039/D2TA02284B10.1039/D2TA02284B ↗
17. 10.1021/jacs.4c0455610.1021/jacs.4c04556 ↗
18. 10.1002/anie.20200479610.1002/anie.202004796 ↗
19. 10.1021/jacs.4c0201510.1021/jacs.4c02015 ↗
20. 10.31635/ccschem.024.20240431110.31635/ccschem.024.202404311 ↗
21. 10.1039/D1CS00983D10.1039/D1CS00983D ↗
22. 10.1002/smll.20230332410.1002/smll.202303324 ↗
23. 10.1002/anie.20241242010.1002/anie.202412420 ↗
24. 10.1021/jacs.3c1154210.1021/jacs.3c11542 ↗
25. 10.1021/jacs.4c0895110.1021/jacs.4c08951 ↗
26. 10.1039/C8CS00978C10.1039/C8CS00978C ↗
27. 10.1002/anie.20241635010.1002/anie.202416350 ↗
28. 10.1038/s41467-024-51950-110.1038/s41467-024-51950-1 ↗
29. 10.1126/science.adq225910.1126/science.adq2259 ↗
30. 10.1002/anie.20211530810.1002/anie.202115308 ↗
31. 10.1016/j.jallcom.2019.15237210.1016/j.jallcom.2019.152372 ↗
32. 10.1002/anie.20190700210.1002/anie.201907002 ↗
33. 10.1021/ja406820f10.1021/ja406820f ↗
34. 10.1021/jp076981k10.1021/jp076981k ↗
35. 10.1021/jacs.4c0084110.1021/jacs.4c00841 ↗
36. 10.1021/acssuschemeng.2c0727110.1021/acssuschemeng.2c07271 ↗
37. 10.1002/anie.20241030010.1002/anie.202410300 ↗
38. 10.1039/b714132g10.1039/b714132g ↗
39. 10.1039/D2SC02319A10.1039/D2SC02319A ↗
40. 10.1039/D2RA02107B10.1039/D2RA02107B ↗
41. 10.1039/C8CY00416A10.1039/C8CY00416A ↗
42. 10.1021/acscatal.8b0389910.1021/acscatal.8b03899 ↗
43. 10.1021/acscatal.9b0391610.1021/acscatal.9b03916 ↗
44. 10.1002/ejic.20210074310.1002/ejic.202100743 ↗
45. 10.1021/ja404695t10.1021/ja404695t ↗
46. 10.1021/acscatal.8b0002110.1021/acscatal.8b00021 ↗
47. 10.1007/s10562-016-1816-410.1007/s10562-016-1816-4 ↗
48. 10.1021/acs.orglett.2c0186710.1021/acs.orglett.2c01867 ↗
49. 10.1002/anie.20210088110.1002/anie.202100881 ↗
50. 10.1038/s41929-022-00783-610.1038/s41929-022-00783-6 ↗
51. 10.1039/D3QM00807J10.1039/D3QM00807J ↗
52. 10.1016/j.apsusc.2018.04.26910.1016/j.apsusc.2018.04.269 ↗
53. 10.1002/anie.20191636010.1002/anie.201916360 ↗
54. 10.1002/anie.20231924710.1002/anie.202319247 ↗
55. 10.1002/chem.20190473110.1002/chem.201904731 ↗
56. 10.1002/er.405810.1002/er.4058 ↗
57. 10.1016/S1872-5805(21)60074-410.1016/S1872-5805(21)60074-4 ↗
58. 10.1002/anie.20240347510.1002/anie.202403475 ↗
59. 10.1002/anie.20241307410.1002/anie.202413074 ↗