journal article·2026-02-02Open access

Surface Induced Order in Room Temperature Ionic Liquids and Its Effect on Piezoelectric Response

Neelanjana Mukherjee, G. J. Blanchard

ACS Materials Letters· Volume 8· Issue 2

Abstract

High Resolution Image Download MS PowerPoint Slide We compare the direct piezoelectric response of the room temperature ionic liquid (RTIL) N -butylpyridinium bis(trifluoromethyl-sulfonyl)imide (C 4 Py TFSI) under conditions where pressure is applied to the bulk RTIL in a vessel with a bare ITO interface and a vessel with an ITO interface modified with a monolayer of a pyridinium-containing amphiphile. We find that the presence of a single monolayer of the pyridinium amphiphile poises the RTIL structurally to produce a measurably larger piezoelectric response. The extent of order imposed by the presence of the monolayer is likely limited by the intrinsic surface roughness and structural irregularity of the ITO-coated glass support used.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Ionic liquids properties and applications · Advanced Sensor and Energy Harvesting Materials · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Michigan State University, Department of Chemistry, 578 S. Shaw Lane, East Lansing, Michigan 48824, United States

Funding

National Science Foundation

References (47)

Show source-provided references
1. 10.1149/1.155906910.1149/1.1559069 ↗
2. 10.1016/j.electacta.2004.03.03010.1016/j.electacta.2004.03.030 ↗
3. 10.1021/bk-2007-0975.ch01010.1021/bk-2007-0975.ch010 ↗
4. 10.2514/1.4995910.2514/1.49959 ↗
5. 10.2514/1.549310.2514/1.5493 ↗
6. 10.1021/ja017593d10.1021/ja017593d ↗
7. 10.1021/sc400274b10.1021/sc400274b ↗
8. 10.1021/ar030252f10.1021/ar030252f ↗
9. 10.2174/15701791279888911610.2174/157017912798889116 ↗
10. 10.1080/00304948.2015.105231710.1080/00304948.2015.1052317 ↗
11. 10.1016/j.molliq.2022.12044710.1016/j.molliq.2022.120447 ↗
12. 10.1039/D1CP05027C10.1039/D1CP05027C ↗
13. 10.1021/acs.jpcb.2c0774510.1021/acs.jpcb.2c07745 ↗
14. 10.1021/acs.jpclett.3c0032910.1021/acs.jpclett.3c00329 ↗
15. 10.1021/acs.jpcb.3c0796710.1021/acs.jpcb.3c07967 ↗
16. 10.1063/5.028112910.1063/5.0281129 ↗
17. 10.1021/acs.langmuir.6b0263910.1021/acs.langmuir.6b02639 ↗
18. 10.1021/acs.langmuir.9b0399510.1021/acs.langmuir.9b03995 ↗
19. 10.1021/acs.jpcb.0c1004510.1021/acs.jpcb.0c10045 ↗
20. 10.1021/acs.langmuir.0c0023710.1021/acs.langmuir.0c00237 ↗
21. 10.1021/acs.jpcc.8b0234510.1021/acs.jpcc.8b02345 ↗
22. 10.1039/D2CP01066F10.1039/D2CP01066F ↗
23. 10.1021/jp912191z10.1021/jp912191z ↗
24. 10.1021/jp400341r10.1021/jp400341r ↗
25. 10.1016/j.molliq.2024.12653910.1016/j.molliq.2024.126539 ↗
26. 10.1016/j.cplett.2015.04.01010.1016/j.cplett.2015.04.010 ↗
27. 10.1063/1.503008310.1063/1.5030083 ↗
28. 10.1021/acs.jpcb.5b0824210.1021/acs.jpcb.5b08242 ↗
29. 10.1016/j.molstruc.2019.01.07610.1016/j.molstruc.2019.01.076 ↗
30. 10.1021/jp409924h10.1021/jp409924h ↗
31. 10.1021/jp210893910.1021/jp2108939 ↗
32. 10.1016/j.fluid.2012.02.00610.1016/j.fluid.2012.02.006 ↗
33. 10.1007/s10953-014-0233-910.1007/s10953-014-0233-9 ↗
34. 10.1080/08957959.2010.52173110.1080/08957959.2010.521731 ↗
35. 10.1016/j.cocis.2017.01.00310.1016/j.cocis.2017.01.003 ↗
36. 10.1039/C7CS00029D10.1039/C7CS00029D ↗
37. 10.3390/cryst1008064810.3390/cryst10080648 ↗
38. 10.3390/pharmaceutics1210099510.3390/pharmaceutics12100995 ↗
39. 10.1021/acsami.7b1504210.1021/acsami.7b15042 ↗
40. 10.1021/ja00210a06210.1021/ja00210a062 ↗
41. 10.1021/ja00048a06510.1021/ja00048a065 ↗
42. 10.1021/ja962021s10.1021/ja962021s ↗
43. 10.1021/ja982552b10.1021/ja982552b ↗
44. 10.1021/la980791710.1021/la9807917 ↗
45. 10.1021/la990668v10.1021/la990668v ↗
46. 10.1149/2.0191508jes10.1149/2.0191508jes ↗
47. 10.1039/D4MH00612G10.1039/D4MH00612G ↗