DataVXACS Materials LettersPaper
journal article·2022-10-03

Controlling the Helicity Direction of Nanoribbons by Circularly Polarized Light

Hongdan Wang, Yang Liu, Lingling Wang, Bikshapathi Raktani, Taehun Yang, Kim My Tran, Yongguang Luo, Jianmin Yu, Haksung Lee, Hyoyoung Lee

ACS Materials Letters· Volume 4· Issue 10
Publisher page
Source abstract

Abstract

Synthesizing helical nanostructures by the noncovalent bonded supramolecular coassembling method has received much attention because it has versatile applications in biological systems. Generating helical polymer structures using circularly polarized (CP) light as a helical source has been limited due to the lack of molecular designs. Herein, we use a new supramolecular organogel sample state to get right- and left-helical nanoribbons produced by right- and left-CP light irradiation. The organogel system consists of long-chain amidoamine (C18AA) and 10,12-pentacosadiynoic acid (PCDA) monomers. The high helicity degree of the nanoribbons was measured by circular dichroism, and the helical direction can be regulated by right-/left-CP light. The helical direction of the right- and left- nanoribbons originated from the right- and left-CP light irradiation of the organogel. Our new concept using CP light in supramolecular organogels may lead to potential applications in biology, pharmacology, and chiral optics.
Source: openalex_inverted_index · Quality: baseline

Research context

PolymersNanomaterials

OpenAlex topics: Synthesis and Properties of Aromatic Compounds · Supramolecular Self-Assembly in Materials · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for Integrated Nanostructure Physics (CINAP), Institute for Basic Science (IBS), Sungkyunkwan University, 2066 Seoburo, Jangan-gu, Suwon 16419, Korea

Department of Chemistry, Sungkyunkwan University, 2066 Seoburo, Jangan-gu, Suwon 16419, Korea

Department of Biophysics, Sungkyunkwan University, 2066 Seoburo, Jangan-gu, Suwon 16419, Korea

Creative Research Institute, Sungkyunkwan University, 2066 Seoburo, Jangan-gu, Suwon 16419, Korea

Funding

Ministry of Health and Welfare · Ministry of Food and Drug Safety · Ministry of Science and ICT, South Korea · Ministry of Trade, Industry and Energy · Institute for Basic Science · Korea Evaluation Institute of Industrial Technology · Scale-up Support Program for Environmental Small-Medium Enterprise

References (47)

Show source-provided references
1. 10.1023/A:100675142591910.1023/A:1006751425919 ↗
2. 10.1002/tcr.20200000410.1002/tcr.202000004 ↗
3. 10.1002/advs.20200213210.1002/advs.202002132 ↗
4. 10.1021/cr500671p10.1021/cr500671p ↗
5. 10.1021/acsnano.7b0609710.1021/acsnano.7b06097 ↗
6. 10.1002/adfm.20200293610.1002/adfm.202002936 ↗
7. 10.1002/anie.20201247010.1002/anie.202012470 ↗
8. 10.1021/jacs.7b0205810.1021/jacs.7b02058 ↗
9. 10.1021/acs.chemrev.6b0035410.1021/acs.chemrev.6b00354 ↗
10. 10.1021/acs.jpclett.1c0086510.1021/acs.jpclett.1c00865 ↗
11. 10.1021/jacs.5b1049610.1021/jacs.5b10496 ↗
12. 10.1039/b813375a10.1039/b813375a ↗
13. 10.1021/cm102276a10.1021/cm102276a ↗
14. 10.1002/anie.20140722310.1002/anie.201407223 ↗
15. 10.1039/C5SC01056J10.1039/C5SC01056J ↗
16. 10.1002/smll.20160084210.1002/smll.201600842 ↗
17. 10.1021/acsami.1c2219110.1021/acsami.1c22191 ↗
18. 10.1002/adma.20190320010.1002/adma.201903200 ↗
19. 10.1039/C9RA01974J10.1039/C9RA01974J ↗
20. 10.1002/anie.20141131310.1002/anie.201411313 ↗
21. 10.1002/tcr.20130004210.1002/tcr.201300042 ↗
22. 10.1039/c2cc17027b10.1039/c2cc17027b ↗
23. 10.1021/jacs.9b0070010.1021/jacs.9b00700 ↗
24. 10.1021/jacs.7b0762610.1021/jacs.7b07626 ↗
25. 10.1039/C6CC09256J10.1039/C6CC09256J ↗
26. 10.1039/C9CC01613A10.1039/C9CC01613A ↗
27. 10.1021/acs.macromol.8b0145310.1021/acs.macromol.8b01453 ↗
28. 10.1039/C4PY01337A10.1039/C4PY01337A ↗
29. 10.1021/acsami.9b1960510.1021/acsami.9b19605 ↗
30. 10.1021/acsami.9b2043810.1021/acsami.9b20438 ↗
31. 10.1016/j.cplett.2007.05.05910.1016/j.cplett.2007.05.059 ↗
32. 10.1038/s41467-018-07533-y10.1038/s41467-018-07533-y ↗
33. 10.1143/JJAP.47.135910.1143/JJAP.47.1359 ↗
34. 10.1039/B210032K10.1039/B210032K ↗
35. 10.1039/b909085a10.1039/b909085a ↗
36. 10.1039/C3CC47245K10.1039/C3CC47245K ↗
37. 10.1021/ja001244m10.1021/ja001244m ↗
38. 10.1038/ncomms795910.1038/ncomms7959 ↗
39. 10.1038/s41578-019-0111-610.1038/s41578-019-0111-6 ↗
40. 10.1039/C7CS00827A10.1039/C7CS00827A ↗
41. 10.1016/j.eurpolymj.2019.05.05610.1016/j.eurpolymj.2019.05.056 ↗
42. 10.1021/acsami.6b1039210.1021/acsami.6b10392 ↗
43. 10.1039/C8SM01515E10.1039/C8SM01515E ↗
44. 10.1002/pat.499010.1002/pat.4990 ↗
45. 10.1021/jacs.8b0091010.1021/jacs.8b00910 ↗
46. 10.1021/bi00742a01510.1021/bi00742a015 ↗
47. 10.1002/adma.20150259010.1002/adma.201502590 ↗