Designing Cage-Supported Cluster-Organic Framework for Highly Efficient Optical Limiting
Source abstract
Abstract
Making metal–organic cages into a cluster-organic framework is rarely known and may bring interesting functions. Ti4L6 (where L = embonate) is an ultrastable tetrahedron that can be used as a 4-connecting crystal engineering tecton. In this work, we first obtain two unique Ti4L6 cage-supported cluster-organic frameworks including the globular [Ba6(μ2–OH)8]4+ cluster and the hollow α-Keggin-type [Zn12(μ3–OH)4(μ2–OH)12]8+ cluster, respectively. Such extraordinary assembly significantly enhances their structural stability, so that both of them have notable optical limiting performances.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Magnetism in coordination complexes · Nanoplatforms for cancer theranostics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, People’s Republic of China
University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China
Funding
National Natural Science Foundation of China · China National Postdoctoral Program for Innovative Talents
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