journal article·2020-04-06

Highly Transparent and Tough Filler Composite Elastomer Inspired by the Cornea

Kenta Watanabe, Eiji Miwa, Fumio Asai, Takahiro Seki, Kenji Urayama, Tomotaka Nakatani, So Fujinami, Taiki Hoshino, Masaki Takata, Chang Liu, Koichi Mayumi, Kohzo Ito, Yukikazu Takeoka

ACS Materials Letters· Volume 2· Issue 4
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Abstract

We propose a strategy to develop a colorless, transparent, and tough composite elastomer inspired by the cornea, which is the transparent front portion of the eyeball. The composite elastomer, in which 34 vol % hard silica particles with a uniform particle size are dispersed as a filler in a low-crosslinking polymer network exhibits a fracture energy that is ∼13.5 times higher than that of a system without the silica particles. This strategy also makes the elastomer optically transparent, because the light scattered by each silica particle that forms an ordered structure in the polymer network is cancelled by interference. This research may pave the way for the development of optically transparent and durable materials for applications such as advanced medical devices and soft robots.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Tactile and Sensory Interactions · Ocular Surface and Contact Lens

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Molecular & Macromolecular Chemistry, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan

Research & Development Center, Unitika, Ltd., 23 Uji-Kozakura, Uji-Shi, Kyoto, 611-0021, Japan

Department of Macromolecular Science & Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan

RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-51982, Japan

Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aobaku, Sendai City, Miyagi 980-8577, Japan

Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

Funding

Japan Science and Technology Agency

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