Unraveling Interfacial Coupling Effects in Cluster Electrocatalysts
Source abstract
Abstract
Single-atom catalysts (SACs) show promise in electrocatalysis because of their high atom utilization and unique properties. While SACs excel in atom efficiency, their isolated sites are limited to a single binding mode, which impedes the capture and coupling of reactants/intermediates in complex reactions. Atomically precise metal cluster catalysts offer more active sites with size- and shape-dependent physiochemical properties and improved activity/selectivity for intricate catalysis. The interfacial coupling in cluster electrocatalysts significantly impacts their properties and binding behaviors. This review focuses on the impact of interfacial coupling in cluster heterostructures on their geometric/electronic structures and electrocatalytic performance. We explore three key coupling effects, cutting-edge characterization techniques, computational simulations, and recent deployments in various electrocatalytic reactions. We also present the challenges and future directions in cluster electrocatalysts for pivotal sustainable energy conversion processes.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · CO2 Reduction Techniques and Catalysts · Ammonia Synthesis and Nitrogen Reduction
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China
School of Materials Science and Engineering, Anhui Polytechnic University, Wuhu, Anhui 241000, China
Funding
Research Grants Council, University Grants Committee · Anhui Polytechnic University · Anhui Provincial Department of Education · Hong Kong Polytechnic University
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