DataVXACS Materials LettersPaper
journal article·2024-03-04

High-Nuclear Alkynyl Cu(I) Cluster-Based Framework for Efficient Xe/Kr Separation

Xi Fan, Kexiu Zuo, Furong Yuan, Yunbin Li, Lu Li, Si Lin, Jiali Huang, Shengchang Xiang, Jia-Qi Wang, Zhangjing Zhang

ACS Materials Letters· Volume 6· Issue 3
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Source abstract

Abstract

MOFs based on high-nuclear clusters as building blocks are specifically attractive but generally unsuitable for efficient Xe/Kr selective separation. In this study, a rare high-nuclear alkynyl Cu 12 cluster-based framework with 1D microchannel ( Cu 12 ) has been successfully developed. Furthermore, the presence of rich tert -butyl and benzene groups within the channels of Cu 12 creates a significant differentiation in the adsorption and binding affinity for Xe and Kr, enabling Cu 12 to efficiently separate Xe from Kr. Significantly, Cu 12 not only presents the first coinage metal cluster-based framework for the challenging gas separation but also possesses the largest cluster core of MOFs reported to date for efficient Xe/Kr separation.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Nanocluster Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, Peoples’s Republic of China

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China

Funding

Natural Science Foundation of Fujian Province · National Natural Science Foundation of China · Education and Research Project of Young and Middle-aged Teachers in Fujian Province

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