Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form
Source abstract
Abstract
Isonicotinic acid (INA), as a prototypical N,O-donor bifunctional ligand, has demonstrated its ability to differentiate Th 4+ from representative ions for products in spent nuclear fuels (Cs +, Ba 2+, Mn 2+, Fe 2+, Fe 3+, Co 2+, Ni 2+, Cu 2+, Pd 2+, ReO 4 –, La 3+, Ce 3+, Ce 4+, UO 2 2+ ), yielding an actinide metal–organic framework, Th-INA-1, by selective crystallization. This unprecedented motif with the highest ligand-binding number (i.e., 16) shows promise as a primary waste form due to its structural integrity, especially exposed to β- or γ-irradiation to achieve doses of 6 MGy.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Radioactive element chemistry and processing · Metal-Organic Frameworks: Synthesis and Applications · Nuclear materials and radiation effects
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, 621900 Mianyang, Sichuan, China
Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraβe 400, 01328 Dresden, Germany
The Rossendorf Beamline at ESRF, The European Synchrotron, CS 40220, 38043 Grenoble Cedex 9, France
Funding
National Natural Science Foundation of China · China Academy of Engineering Physics
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