journal article·2023-03-06

Enhancing Efficiency of Organic Solar Cells with Alkyl Diamines Doped PEDOT: PSS

Weixuan Liang, Jiaxing Huang, Zejun Wang, Ciyuan Huang, Qi Wei, Chenghui Liao, Ruijie Ma, Tao Liu, Weiya Zhu, Yuan Li

ACS Materials Letters· Volume 5· Issue 3
Publisher page

Abstract

Poly(3,4-ethylenedioxythiophene): poly(styrene-sulfonate) (PEDOT: PSS) has been the most popular conductive polymer as a hole transport material in organic solar cells (OSCs). Modification of PEDOT: PSS can improve its various properties to realize high performance in OSCs. The conductivity of PEDOT: PSS is an essential factor in determining device performance. In this work, PEDOT: PSS-BA, PEDOT: PSS-HA, and PEDOT: PSS-OA are prepared via facile doping of corresponding alkyl diamines into PEDOT: PSS, considering the amino ion can interact with redundant sulfonic acid groups of PSS. All the modified products exhibit enhanced conductivities due to their more ordered molecular packing comparing PEDOT: PSS. Using PTQ10 and m-BTP-PhC6 as the binary active layer, the OSC devices based on PEDOT: PSS-BA yield a superior power conversion efficiency of 18.44%, which ranks as one of the highest values in the binary OSCs.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Conducting polymers and applications · Organic Electronics and Photovoltaics · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, P. R. China

State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China

Department of Electronic and Information Engineering, Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China

Funding

Guangxi University · Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program · Central University Basic Research Fund of China · National Natural Science Foundation of China · Hong Kong Polytechnic University · Key Laboratory of Optoelectronic Chemical Materials and Devices · Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, South China University of Technology

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