Covalently Functionalized MoS2 with Dithiolenes
Source abstract
Abstract
Advances are required to develop functionalization routes for MoS2, in both the metallic 1T and semiconducting 2H phase, that will not only enable their easier manipulation and handling in liquid media but also enhance their applicability in diverse technological fields. Herein, we report an original functionalization methodology for covalently incorporating dithiolene units at the periphery of exfoliated 1T- and 2H-MoS2 sheets, by employing a bis(thiolate) salt as a ligand in a green and facile protocol. Extensive characterization of the covalently functionalized materials is presented, along with a pathway for the à la carte chemical manipulation of MoS2. Markedly, the reported methodology may be applied for modifying other transition metal dichalcogenides.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: 2D Materials and Applications · MXene and MAX Phase Materials · Perovskite Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, 11635 Athens, Greece
Laboratorio de Microscopias Avanzadas, Instituto de Nanociencia de Aragon, Universidad de Zaragoza, 50018 Zaragoza, Spain
ARAID Foundation, 50018 Zaragoza, Spain
Instituto de Ciencias de Materiales Aragon, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain
Funding
European Commission · Ministerio de Econom??a y Competitividad · General de Arag??n · Ministry of Economy and Development
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