journal article·2024-12-02

Reduced-Symmetry Ligand Constructed Y-Based Metal–Organic Framework for Inverse Propane/Propylene Separation

Yonghua Zhong, Zi-Ming Ye, Fanrui Sha, Haomiao Xie, Xiaoliang Wang, Chenghui Zhang, Daofei Lv, Yongwei Chen, Zhibo Li, Omar K. Farha

ACS Materials Letters· Volume 6· Issue 12
Publisher page

Abstract

The rational design of organic ligands is crucial in the development of new metal–organic frameworks (MOFs) to enrich the structural diversity and application potential of MOFs. For example, tuning the ligand symmetry has been widely utilized in the construction of new MOFs with specific properties. Herein, a novel Y-based MOF (denoted as NU-60) was generated by selecting a tritopic carboxylate ligand with reduced symmetry. Compared with its tritopic counterpart with relatively high symmetry, NU-60 has a new (3,12)-connected topology, highlighting the power of the ligand desymmetrization method to enrich MOF structural diversity. Gas adsorption studies demonstrated that NU-60 is a propane-selective adsorbent for efficient propane/propylene separation.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Zeolite Catalysis and Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

School of Environment and Chemical Engineering, Foshan University, Foshan 528000, China

Department of Chemical and Biological Engineering, Northwestern University, Evanston, Illinois 60208, United States

Funding

National Outstanding Youth Science Fund Project of National Natural Science Foundation of China · China Postdoctoral Science Foundation · Natural Science Foundation of Guangdong Province · Natural Science Foundation of Shandong Province · Taishan Scholar Constructive Engineering Foundation

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