journal article·2022-06-06

Modulating Photo- and Radioluminescence in Tb(III) Cluster-Based Metal–Organic Frameworks

Zvart Ajoyan, Gabrielle A. Mandl, P. Rafael Donnarumma, Victor Quezada-Novoa, Hudson A. Bicalho, Hatem M. Titi, John A. Capobianco, Ashlee J. Howarth

ACS Materials Letters· Volume 4· Issue 6
Publisher page

Abstract

Luminescent metal–organic frameworks (MOFs) are of interest for sensing, theranostics, dosimetry, and other applications. The use of lanthanoids in MOF nodes allows for intrinsic metal-based luminescence. In this work, a facile route for modulating the photoluminescent and radioluminescent properties of Tb(III)-based MOFs is reported. By using Tb(III) cluster nodes as X-ray attenuators, and organic linkers with varying excited state energies as sensitizers, MOFs with metal-based, linker-based, and metal+linker-based photo- and radioluminescence are reported.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Lanthanide and Transition Metal Complexes · Nanocluster Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Biochemistry and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke Street West, Montreal, Quebec H4B 1R6, Canada

FRQNT Quebec Centre for Advanced Materials (QCAM/CQMF), 3420 University, Montreal, Quebec H3A 2A7, Canada

Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada

Funding

Concordia University · Natural Sciences and Engineering Research Council of Canada

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