journal article·2016-11-11

From the Junkyard to the Power Grid: Ambient Processing of Scrap Metals into Nanostructured Electrodes for Ultrafast Rechargeable Batteries

Nitin Muralidharan, Andrew S. Westover, Haotian Sun, Nicholas Galioto, Rachel E. Carter, Adam P. Cohn, Landon Oakes, Cary L. Pint

ACS Energy Letters· Volume 1· Issue 5
Publisher page

Abstract

Here we present the first full cell battery device that is developed entirely from scrap metals of brass and steel—two of the most commonly used and discarded metals. A room-temperature chemical process is developed to convert brass and steel into functional electrodes for rechargeable energy storage that transforms these multicomponent alloys into redox-active iron oxide and copper oxide materials. The resulting steel–brass battery exhibits cell voltages up to 1.8 V, energy density up to 20 Wh/kg, power density up to 20 kW/kg, and stable cycling over 5000 cycles in alkaline electrolytes. Further, we show the versatility of this technique to enable processing of steel and brass materials of different shapes, sizes, and purity, such as screws and shavings, to produce functional battery components. The simplicity of this approach, building from chemicals commonly available in a household, enables a simple pathway to the local recovery, processing, and assembly of storage systems based on materials that would otherwise be discarded.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced battery technologies research · Advancements in Battery Materials · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Interdisciplinary Materials Science Program and ‡Department of Mechanical Engineering, Vanderbilt University, Nashville, Tennessee 37235, United States

Funding

Vanderbilt University · National Aeronautics and Space Administration

References (60)

Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. 10.1021/ja309143810.1021/ja3091438 ↗
3. 10.1038/3510464410.1038/35104644 ↗
4. 10.1007/s10008-011-1386-810.1007/s10008-011-1386-8 ↗
5. 10.2307/2775765710.2307/27757657 ↗
6. 10.1016/0378-7753(91)80002-F10.1016/0378-7753(91)80002-F ↗
7. 10.1038/ncomms192110.1038/ncomms1921 ↗
8. 10.1016/0378-7753(94)01953-310.1016/0378-7753(94)01953-3 ↗
9. 10.1126/science.121274110.1126/science.1212741 ↗
10. 10.1016/j.pnsc.2008.07.01410.1016/j.pnsc.2008.07.014 ↗
11. 10.1039/c2ra21342g10.1039/c2ra21342g ↗
12. 10.1021/cr300205k10.1021/cr300205k ↗
13. Campbell T. · 2011
14. 10.1039/C5CS00714C10.1039/C5CS00714C ↗
15. 10.5437/08956308X560619310.5437/08956308X5606193 ↗
16. 2015
17. Goonan T. G. · 2010
18. 10.1016/S0921-3449(97)00033-510.1016/S0921-3449(97)00033-5 ↗
19. Damuth R. J. · 2010
20. 10.1021/jp054350p10.1021/jp054350p ↗
21. 10.1002/anie.20046245910.1002/anie.200462459 ↗
22. 10.1038/srep0754710.1038/srep07547 ↗
23. 10.1021/nl102203s10.1021/nl102203s ↗
24. 10.1021/acsenergylett.6b0006710.1021/acsenergylett.6b00067 ↗
25. 10.1039/c4ra00018h10.1039/c4ra00018h ↗
26. 10.1021/acsami.5b1054710.1021/acsami.5b10547 ↗
27. 10.1039/C5RA24579F10.1039/C5RA24579F ↗
28. 10.1016/j.jelechem.2014.09.00410.1016/j.jelechem.2014.09.004 ↗
29. 10.1016/j.jclepro.2015.07.08310.1016/j.jclepro.2015.07.083 ↗
30. 10.1021/acsami.5b1210710.1021/acsami.5b12107 ↗
31. 10.1007/s10854-016-4958-710.1007/s10854-016-4958-7 ↗
32. 10.1088/0957-4484/23/50/50540110.1088/0957-4484/23/50/505401 ↗
33. 10.2147/IJN.S8283010.2147/IJN.S82830 ↗
34. 10.1016/j.matchemphys.2014.06.04710.1016/j.matchemphys.2014.06.047 ↗
35. 10.1039/b201561g10.1039/b201561g ↗
36. 10.4067/S0717-9707201000010003410.4067/S0717-97072010000100034 ↗
37. 10.1039/C0JM03022H10.1039/C0JM03022H ↗
38. 10.1039/c3cp51213d10.1039/c3cp51213d ↗
39. 10.1126/science.124962510.1126/science.1249625 ↗
40. 10.1149/2.0201505jes10.1149/2.0201505jes ↗
41. 10.1038/ncomms825910.1038/ncomms8259 ↗
42. 10.1016/0378-7753(84)80018-X10.1016/0378-7753(84)80018-X ↗
43. 10.1016/j.jpowsour.2011.01.03210.1016/j.jpowsour.2011.01.032 ↗
44. 10.1021/nl400760a10.1021/nl400760a ↗
45. 10.1149/1.161445110.1149/1.1614451 ↗
46. 10.1016/j.jpowsour.2010.07.06610.1016/j.jpowsour.2010.07.066 ↗
47. 10.1039/c4ra01793e10.1039/c4ra01793e ↗
48. 10.1039/C4TA01296H10.1039/C4TA01296H ↗
49. 10.1007/s00339-005-3401-310.1007/s00339-005-3401-3 ↗
50. 10.1021/nl302761z10.1021/nl302761z ↗
51. 10.1016/j.jpowsour.2007.08.11510.1016/j.jpowsour.2007.08.115 ↗
52. 10.1038/srep0332310.1038/srep03323 ↗
53. 10.1016/j.jpowsour.2015.11.06510.1016/j.jpowsour.2015.11.065 ↗
54. 10.1038/am.2015.3210.1038/am.2015.32 ↗
55. 10.1002/aelm.20150029610.1002/aelm.201500296 ↗
56. 10.1002/er.349910.1002/er.3499 ↗
57. 10.1002/adma.20140463910.1002/adma.201404639 ↗
58. 10.1016/j.jpowsour.2016.05.13810.1016/j.jpowsour.2016.05.138 ↗
59. 10.1016/S0925-8388(99)00006-710.1016/S0925-8388(99)00006-7 ↗
60. 10.1016/S0378-7753(01)01014-X10.1016/S0378-7753(01)01014-X ↗