Formal Oxidation States and Coordination Environments in the Catalytic Reduction of CO to Methanol
Source abstract
Abstract
Fundamental insight into multielectron, multiproton redox reactions with organometallic catalysts is greatly facilitated by knowledge of the formal oxidation state of the metal center in each of the elementary reaction steps that comprise the catalytic cycle. X-ray absorption near edge structure (XANES) is utilized herein to quantify the oxidation states and coordination environment of the organometallic resting state and intermediates in a newly proposed catalytic reduction of carbon monoxide to methanol.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science · CO2 Reduction Techniques and Catalysts
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973-5000, United States
Synchrotron Science Group, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States
Photon Science Department, Brookhaven National Laboratory, Upton, New York 11973-5000, United States
Department of Chemistry, University of North Carolina Chapel Hill, Chapel Hill, North Carolina 27599, United States
Funding
Energy Frontier Research Centers · Basic Energy Sciences
References (15)
Show source-provided references
1. Collman J. P. · 1987
2. Jorgenson C. K. · 196910.1007/978-3-642-87758-2 ↗
3. 10.1002/anie.20200837010.1002/anie.202008370 ↗
4. 10.1021/jacs.3c1460510.1021/jacs.3c14605 ↗
5. 10.1021/jp303828510.1021/jp3038285 ↗
6. 10.1016/j.ica.2007.07.02910.1016/j.ica.2007.07.029 ↗
7. 10.1021/jp990096n10.1021/jp990096n ↗
8. 10.1021/jp401020j10.1021/jp401020j ↗
9. 10.1021/acs.inorgchem.0c0066310.1021/acs.inorgchem.0c00663 ↗
10. 10.1039/D0SC06227H10.1039/D0SC06227H ↗
11. 10.1063/1.45462810.1063/1.454628 ↗
12. 10.1021/ic00093a03310.1021/ic00093a033 ↗
13. 10.1021/ja00374a01910.1021/ja00374a019 ↗
14. 10.1021/om980102m10.1021/om980102m ↗
15. 10.1039/C6CS00230G10.1039/C6CS00230G ↗