journal article·2025-12-31Open access

Sum rules for X-ray circular and linear dichroism based on complete magnetic multipole basis

Y. Yamasaki, Y. Ishii, N. Sasabe

Abstract

X-ray magnetic circular dichroism (XMCD) and X-ray magnetic linear dichroism (XMLD) are powerful spectroscopic techniques for probing magnetic properties in solids. In this study, we revisit the XMCD and XMLD sum rules within a complete magnetic multipole basis that incorporates both spinless and spinful multipoles. We demonstrate that these multipoles can be clearly distinguished and individually detected through the sum-rule formalism. Within this framework, the anisotropic magnetic dipole term is naturally derived in XMCD, offering a microscopic origin for ferromagnetic-like behavior in antiferromagnets. Furthermore, we derive the sum rules for out-of-plane and in-plane XMLD regarding electric quadrupole contributions defined based on the complete multipole basis. Our theoretical approach provides a unified, symmetry-consistent framework for analyzing dichroic signals in various magnetic materials. These findings deepen the understanding of XMCD and XMLD and open pathways to exploring complex magnetic structures and spin-orbit coupling effects in emergent magnetic materials.
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Research context

OpenAlex topics: Magnetic properties of thin films · Iron oxide chemistry and applications · Characterization and Applications of Magnetic Nanoparticles

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute for Materials Science (NIMS)

Tohoku University

Center for Emergent Matter Science (CEMS), RIKEN

Funding

Core Research for Evolutional Science and Technology · Japan Society for the Promotion of Science · Ministry of Education, Culture, Sports, Science and Technology · PRESTO

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