journal article·2022-06-10

A “Li-Eye” View of Diffusion Pathways in a 2D Intercalation Material from Topochemical Single-Crystal Transformation

Joseph V. Handy, Justin L. Andrews, Saul Perez-Beltran, Daniel R. Powell, Ryan Albers, Luisa Whittaker-Brooks, Nattamai Bhuvanesh, Sarbajit Banerjee

ACS Energy Letters· Volume 7· Issue 6
Publisher page

Abstract

We use single-crystal-to-single-crystal transformations to directly image with sub-angstrom resolution distortions of the host lattice, Li site occupancies, and diffusion pathways in a 2D metastable intercalation material. We capture atomistic descriptions of Li-ion diffusion pathways and reconstruct a Li-eye view of available interstitial sites through a 2D intercalation host to address a long-standing challenge in the design of cathode materials and pave the way to atom-precise structural modifications.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Advancements in Battery Materials · Multiferroics and related materials

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Affiliations

Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States

Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States

Department of Materials Science & Engineering, Texas A&M University, College Station, Texas 77843, United States

Funding

National Science Foundation

References (10)

Show source-provided references
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