A La 2 O 3 /MXene composite electrode for supercapacitors with improved capacitance and cycling performance
Source abstract
Abstract
Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and cycling performance. Considering this challenge, here we have designed a composite made of 2D MXene nanosheets and lanthanum oxide (La2O3) nanoparticles to overcome the limitations. The bifunctionality of La2O3 nanoparticle prevents the restacking of MXene layers and enhances the electrochemical properties of the electrode due to its good Faradic characteristics. The specific capacitance of the La2O3/MXene composite electrode is 366 F/g at 1 A/g, which is 4.5 and 3 times higher than those of the individual La2O3 and MXene. The composite electrode displays a capacitance retention of 96% after 1,000 cycles, which is due to synergistic effect between the two components and indicates the potential of La2O3/MXene composite for supercapacitors.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: MXene and MAX Phase Materials · Supercapacitor Materials and Fabrication · Advanced Memory and Neural Computing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Tsinghua University
Narowal Campus, University of Engineering and Technology
Zhejiang Sci-Tech University
Funding
National Natural Science Foundation of China · Guangdong Basic and Applied Basic Research Foundation · the Shenzhen Basic Research Project
References (66)
Show source-provided references
1. 10.1039/C9NA00307J10.1039/C9NA00307J ↗
2. 10.1016/j.elecom.2017.12.01710.1016/j.elecom.2017.12.017 ↗
3. 10.1002/anie.20141037610.1002/anie.201410376 ↗
4. 10.1126/science.121274110.1126/science.1212741 ↗
5. 10.1016/j.cej.2021.13186010.1016/j.cej.2021.131860 ↗
6. 10.1039/D1TA10444F10.1039/D1TA10444F ↗
7. 10.1039/C5CS00580A10.1039/C5CS00580A ↗
8. 10.1039/C7CS00505A10.1039/C7CS00505A ↗
9. 10.1016/j.jpowsour.2010.09.05710.1016/j.jpowsour.2010.09.057 ↗
10. 10.1109/TDC-LA.2012.631905110.1109/TDC-LA.2012.6319051 ↗
11. 10.1016/S0378-7753(02)00718-810.1016/S0378-7753(02)00718-8 ↗
12. 10.1088/0957-4484/17/21/00510.1088/0957-4484/17/21/005 ↗
13. 10.1038/s41578-019-0142-z10.1038/s41578-019-0142-z ↗
14. 10.1016/j.electacta.2019.02.09210.1016/j.electacta.2019.02.092 ↗
15. 10.1039/c1cc14030b10.1039/c1cc14030b ↗
16. 10.1021/acs.energyfuels.1c0274310.1021/acs.energyfuels.1c02743 ↗
17. 10.1002/sstr.20220010910.1002/sstr.202200109 ↗
18. 10.1002/smm2.115610.1002/smm2.1156 ↗
19. 10.1038/s41565-022-01186-110.1038/s41565-022-01186-1 ↗
20. 10.1038/s41467-020-17121-810.1038/s41467-020-17121-8 ↗
21. 10.1038/s41467-021-26315-710.1038/s41467-021-26315-7 ↗
22. 10.1007/s11467-015-0493-x10.1007/s11467-015-0493-x ↗
23. 10.1016/j.cossms.2019.01.00210.1016/j.cossms.2019.01.002 ↗
24. 10.1088/0953-8984/26/50/50550310.1088/0953-8984/26/50/505503 ↗
25. 10.1016/j.nanoen.2020.10473410.1016/j.nanoen.2020.104734 ↗
26. 10.1016/j.ensm.2022.10.00510.1016/j.ensm.2022.10.005 ↗
27. 10.1039/D2NR02802F10.1039/D2NR02802F ↗
28. Tiwari A, Dixit A. Rare earth oxides based composites for high voltage supercapacitors applications: a short review. Renewable Energy and Climate Change: Proceedings of REC. Gujarat, India. 2019;2020:1–10.
29. 10.1016/j.ceramint.2015.09.09810.1016/j.ceramint.2015.09.098 ↗
30. 10.1016/j.electacta.2017.04.17510.1016/j.electacta.2017.04.175 ↗
31. 10.1016/j.inoche.2022.10933110.1016/j.inoche.2022.109331 ↗
32. 10.1002/admi.20180200410.1002/admi.201802004 ↗
33. 10.1002/adfm.20150532810.1002/adfm.201505328 ↗
34. 10.1021/acs.energyfuels.0c0135210.1021/acs.energyfuels.0c01352 ↗
35. Kumar PR, Maharajan TM, Chinnasamy M, et al. Hydroxyl radical scavenging activity of La2O3 nanoparticles. J Pharm Innov. 2019;8:759–763.
36. 10.1021/acs.energyfuels.0c0095910.1021/acs.energyfuels.0c00959 ↗
37. 10.1021/acs.chemmater.0c0035910.1021/acs.chemmater.0c00359 ↗
38. 10.1021/acsami.6b0476710.1021/acsami.6b04767 ↗
39. 10.1155/2015/94017210.1155/2015/940172 ↗
40. 10.1021/acs.iecr.9b0101810.1021/acs.iecr.9b01018 ↗
41. 10.1021/acsomega.7b0200110.1021/acsomega.7b02001 ↗
42. 10.1021/acs.chemmater.7b0284710.1021/acs.chemmater.7b02847 ↗
43. 10.1039/D0RA10018H10.1039/D0RA10018H ↗
44. 10.1021/nn204153h10.1021/nn204153h ↗
45. 10.3390/chemosensors908022510.3390/chemosensors9080225 ↗
46. 10.1002/cssc.20180303210.1002/cssc.201803032 ↗
47. 10.1002/wcms.131310.1002/wcms.1313 ↗
48. 10.1016/j.ceramint.2023.03.23810.1016/j.ceramint.2023.03.238 ↗
49. 10.1039/C7RA00184C10.1039/C7RA00184C ↗
50. 10.1007/s10854-021-05264-310.1007/s10854-021-05264-3 ↗
51. 10.5599/jese.63710.5599/jese.637 ↗
52. 10.1021/acs.energyfuels.0c0393910.1021/acs.energyfuels.0c03939 ↗
53. 10.1016/j.electacta.2016.09.06910.1016/j.electacta.2016.09.069 ↗
54. 10.1016/j.jelechem.2019.11371010.1016/j.jelechem.2019.113710 ↗
55. 10.1016/j.jpowsour.2019.02.05910.1016/j.jpowsour.2019.02.059 ↗
56. 10.1016/j.electacta.2017.04.17510.1016/j.electacta.2017.04.175 ↗
57. 10.1016/j.jelechem.2012.06.01610.1016/j.jelechem.2012.06.016 ↗
58. 10.1016/j.ceramint.2020.01.22210.1016/j.ceramint.2020.01.222 ↗
59. 10.1007/s42114-021-00323-z10.1007/s42114-021-00323-z ↗
60. 10.1007/s10853-019-04003-810.1007/s10853-019-04003-8 ↗
61. 10.1149/1945-7111/acbee510.1149/1945-7111/acbee5 ↗
62. 10.1016/j.nanoen.2021.10624210.1016/j.nanoen.2021.106242 ↗
63. 10.1016/j.ceramint.2022.03.22610.1016/j.ceramint.2022.03.226 ↗
64. 10.1016/j.electacta.2021.13824510.1016/j.electacta.2021.138245 ↗
65. 10.1021/acsnano.7b0724110.1021/acsnano.7b07241 ↗
66. 10.1016/j.jpowsour.2016.07.06210.1016/j.jpowsour.2016.07.062 ↗