In situ ligand synthesis affording a new Co(ii) MOF for photocatalytic application
Source abstract
Abstract
Abstract In situ disulfide bond formation affords a new flexible dicarboxylic acid ligand of 3,3′-dithiobisbenzoic acid (3,3′-H 2 DTBA), which assembled with Co( ii ) ions under hydrothermal conditions, generating a novel metal–organic framework (MOF), namely, [Co(3,3′-DTBA) 2 (H 2 O) 2 ] n ( 1 ). This compound is assembled from layered structures, featuring weak interlayer interactions that can reduce pore blockage through relative sliding. The results of photocatalytic experiment indicate that MOF 1 is a good semiconducting material and it can function as photocatalyst for degrading methylene blue under the ultraviolet light irradiation. Cyclic experiments demonstrated its good stability and long-lasting photocatalytic performance, indicating its potential application value.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Corrosion Behavior and Inhibition · MXene and MAX Phase Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, Key Laboratory of Chemistry of New Material of Functional Inorganic Composites, School of Chemical Engineering, Xi’an University , Xi’an , Shaanxi , China
References (23)
Show source-provided references
1. Allendorf MD, Bauer CA, Bhakta RK. Luminescent metal-organic frameworks. Chem Soc Rev. 2009;38:1330–52.10.1039/b802352m ↗
2. Lee J, Farha QK, Roberts J, Scheidt KA, Nguyen ST, Hupp JT. Metal-organic framework materials as catalysts. Chem Soc Rev. 2009;38:1450–9.10.1039/b807080f ↗
3. Seth S, Savitha G, Moorthy JN. Carbon dioxide capture by a metal-organic framework with nitrogen-rich channels based on rationally designed triazole-functionalized tetraacid organic linker. Inorg Chem. 2015;54:6829–35.10.1021/acs.inorgchem.5b00722 ↗
4. Pei RB, Cao MY, Li LK, Dong XY, Zang SQ. A series of transition metal-organic frameworks based on a bipyridinium carboxylate ligand: Syntheses, structures and photoluminescent properties. J Mol Struct. 2017;1143:72–83.10.1016/j.molstruc.2017.04.075 ↗
5. Ghasempour H, Wang KY, Powell JA, Zarekarizi F, Lv XL, Morsali A, et al. Metal-organic frameworks based on multicarboxylate linkers. Coord Chem Rev. 2021;426:213542.10.1016/j.ccr.2020.213542 ↗
6. Zhang Y, Liu Y, Liu Z, Wu X, Wen Y, Chen H, et al. MnO2 cathode materials with the improved stability via nitrogen doping for aqueous zinc-ion batteries. J Energy Chem. 2022;64:23–32.10.1016/j.jechem.2021.04.046 ↗
7. Parveen N, Ansari SA, Ansari MZ, Ansari MO. Manganese oxide as an effective electrode material for energy storage: a review. Environ Chem Lett. 2022;20:283–309.10.1007/s10311-021-01316-6 ↗
8. Abbas N, Shaheen I, Hussain I, Lamiel C, Ahmad M, Ma X, et al. Glycerol-mediated synthesis of copper-doped zinc sulfide with ultrathin nanoflakes for flexible energy electrode materials. J Alloys Compd. 2022;919:165701.10.1016/j.jallcom.2022.165701 ↗
9. Hussain I, Ansari MZ, Lamiel C, Hussain T, Javed MS, Kaewmaraya T, et al. In situ grown heterostructure based on MOF-derived carbon containing n-Type Zn–In–S and dry-oxidative p-Type CuO as pseudocapacitive electrode materials. ACS Energy Lett. 2023;8:1887–95.10.1021/acsenergylett.3c00221 ↗
10. An YY, Liu LP, Zhu ML. Construction of a new (4,8)-connected coordination polymer based on the zinc cluster: structure, topology, and luminescence. Chin J Struct Chem. 2018;37:1479–85.
11. Zhang J, Chen S, Bu X. Multiple functions of ionic liquids in the synthesis of 3-D low-connectivity homochiral and achiral frameworks. Angew Chem Int Ed. 2008;47:5434–7.10.1002/anie.200801838 ↗
12. Wang Y, Yang GP, Zhang PF, Ma LL, Wang JM, Li GP, et al. Microporous Cd(ii) metal-organic framework for CO2 catalysis, luminescent sensing, and absorption of methyl green. Cryst Growth Des. 2021;21:2734–43.10.1021/acs.cgd.0c01602 ↗
13. Chen YQ, Zhai JX, Tian Y, Liu XP. Auxiliary ligand oriented Cd(ii)-flexible dicarboxylic acid coordination frameworks: syntheses, structures and properties. Chin J Struct Chem. 2019;38:1311–9.
14. Weng Z, Xiang P, Ling J, Huang M, Yang W, Zheng Z, et al. In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework. J Solid State Chem. 2020;287:121326.10.1016/j.jssc.2020.121326 ↗
15. Zhang L, Li ZJ, Qin YY, Zhang J, Cheng JK, Yin PX, et al. pH-controlled assembly of two supramolecular architectures based on Cu(ii)-metallacycle building blocks. J Mol Struct. 2008;891:138–42.10.1016/j.molstruc.2008.03.015 ↗
16. Yuan N, Sheng T, Zhang J, Tian C, Hu S, Huang X, et al. A disulfide ligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer. CrystEngComm. 2011;13:5951–5.10.1039/c1ce05154g ↗
17. Lin L, Zhang X, Zhang J, Yao YG. Hydrothermal in situ ligand synthesis and chiral self-assembly with Pr(iii). J Mol Struct. 2011;1006:83–6.10.1016/j.molstruc.2011.07.033 ↗
18. Chen F, Wu MF, Liu GN, Wang MS, Zheng FK, Yang C, et al. Zinc(ii) and cadmium(ii) coordination polymers based on 3-(5H-tetrazolyl)benzoate ligand with different coordination modes: hydrothermal syntheses, crystal structures and ligand-centered luminescence. Eur J Inorg Chem. 2010;31:4982–91.10.1002/ejic.201000578 ↗
19. Dong R, Chen X, Li Q, Hu M, Huang L, Li C, et al. (1H-tetrazol-5-yl) methyl) pyridine-based metal coordination complexes: in situ tetrazole synthesis, crystal structures, luminescence properties. CrystEngComm. 2015;17:1305–17.10.1039/C4CE01981D ↗
20. Rowland CE, Belai N, Knope KE, Cahill CL. Hydrothermal synthesis of disulfide-containing uranyl compounds: in situ ligand synthesis versus direct assembly. Cryst Growth Des. 2010;10:1390–8.10.1021/cg901390n ↗
21. Sheldrick GM. Crystal structure refinement with SHELXL. Acta Crystallogr. Sect C: Struct Chem. 2015;71:3–8.10.1107/S2053229614024218 ↗
22. Wang XF, Guo XY, Liu T. Two Co(ii) based coordination polymers constructed from π-electron rich polycarboxylate aryl ether ligand: structural insights and photocatalytic dye degradation. Chin J Struct Chem. 2021;6:722–8.
23. Zhang D, Bi C, Zong Z, Fan Y. Three different Co(ii) metal–organic frameworks based on 4,4′‑bis(imidazolyl)diphenyl ether: syntheses, crystal structure and photocatalytic properties. J Inorg Organomet Poly. 2020;30:5148–56.10.1007/s10904-020-01657-9 ↗