journal article·2026-03-13

Biphasic and Triphasic Oxide Cathode Materials for Advanced Na-Ion Batteries

Feng Li, Mohan Dong, Huijie Bian, Peiyu Hou, Zezhou Lin, Linhui Wang, Xijin Xu

ACS Energy Letters· Volume 11· Issue 3
Publisher page

Abstract

Low-cost Na-ion batteries (NIBs) hold significant potential for grid energy storage. Na x TMO 2 oxides are considered one of the cathode candidates for NIBs. However, the phase transitions and Jahn–Teller distortion lead to their structural decay and performance decline. The synergistic effects arising from the combination of O-type, P-type, tunnel, and spinel structures can enhance their electrochemical properties. Recent studies in biphasic and triphasic intergrowth present considerable potential for addressing the aforementioned challenges. In this Review, we first comprehensively discuss the main strategies for synthesizing biphasic and triphasic oxides. Then, recent advancements in multiphase oxide cathodes for NIBs are further summarized, with a focus on their electrochemical behaviors and reaction mechanisms. Finally, the persistent challenges and future opportunities for the multiphase oxide cathodes are outlined. This Review aims to provide a profoundly significant guiding framework for the rational design of multiphase oxide cathodes for advanced NIBs.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Physics and Technology

University of Jinan

Department of Applied Physics and Research Institute of Smart Energy

The Hong Kong Polytechnic University

College of Information Science and Engineering

Shandong Agricultural University

Funding

Taishan Scholar Project of Shandong Province · Postdoctoral Innovation Project of Shandong Province · National Natural Science Foundation of China

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