Synthesis, thermal and magnetic behavior of iron oxide-polymer nanocomposites
Source abstract
Abstract
Abstract Polymer nanocomposites of various concentrations were prepared using iron oxide (Fe 2 O 3 ) nanoparticles as filler in an 80:20 ratio of the polyurethane diol and polycaprolactone hybrid. Fourier transformed infrared spectroscopy studies were performed to find out the interaction of the nanoparticles with the polymer blend. Fe 2 O 3 in the polymer composites was in the nanoscale and uniform dispersion was achieved, as revealed by X-ray diffraction. The thermal stability of the blend was assessed through thermogravimetry analysis and dynamic mechanical analysis. High-resolution scanning electron microscopy and transmission electron microscopy images ensured the development of the polymer hybrid around Fe 2 O 3 nanoparticles and the prepared composites were indeed in the nanoscale. The magnetic behavior of the prepared nanocomposites is superparamagnetic with high magnetization values, as assessed by vibrating sample magnetometry analysis.
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Research context
OpenAlex topics: Polymer Nanocomposites and Properties · Iron oxide chemistry and applications · Nanoparticle-Based Drug Delivery
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry , St. Xavier’s Catholic College of Engineering , Nagercoil , Tamil Nadu, India
Department of Chemistry , University College of Engineering , Nagercoil , Anna University Constituent College, Tamil Nadu, India
SRM Research Institute , Department of Chemistry , SRM University , SRM Nagar , Kattankulathur , Tamilnadu, India
References (46)
Show source-provided references
1. Baskaran R, Selvasekarapandian S, Kuwata N, Kawamura J, Hattori T. Mater. Chem. Phys. 2006, 98, 55–56.10.1016/j.matchemphys.2005.08.06310.1016/j.matchemphys.2005.08.063 ↗
2. Sivakumar M, Subadevi R, Rajendran S, Wu H-C, Wu N-L. Eur. Polym. J. 2007, 43, 4466–4473.10.1016/j.eurpolymj.2007.08.00110.1016/j.eurpolymj.2007.08.001 ↗
3. Fan LZ, Dang ZM, Nan CW, Li M. J. Electrochim. Acta 2002, 48, 205–209.10.1016/S0013-4686(02)00603-510.1016/S0013-4686(02)00603-5 ↗
4. Ramesh S, Winie T, Arof AK. Eur. Polym. J. 2007, 43, 1963–1968.10.1016/j.eurpolymj.2007.02.00610.1016/j.eurpolymj.2007.02.006 ↗
5. Zhu G, Liang G, Xu Q, Yu Q. J. Appl. Polym. Sci. 2003, 90, 1589–1595.10.1002/app.1273610.1002/app.12736 ↗
6. Ping P, Wang W, Chen X, Jing X. Biomacromolecules 2005, 6, 587–592.10.1021/bm049477j10.1021/bm049477j ↗
7. Meng Q, Hu J. Polym. Adv. Technol. 2008, 19, 131–136.10.1002/pat.985 ↗
8. Nair LS, Laurencin CT. Prog. Polym. Sci. 2007, 32, 762–798.10.1016/j.progpolymsci.2007.05.01710.1016/j.progpolymsci.2007.05.017 ↗
9. Sunija AJ, Sivailango S, Vinodkumar KP. Bull. Mater. Sci. 2014, 37, 735–741.10.1007/s12034-014-0665-210.1007/s12034-014-0665-2 ↗
10. Santerre JP, Woodhouse K, Laroche G. Biomaterials 2005, 26, 7457–7470.10.1016/j.biomaterials.2005.05.07910.1016/j.biomaterials.2005.05.079 ↗
11. Khatiwala VK, Shekhar N, Aggarwal S, Mandal UK. J. Polym. Environ. 2008, 16, 61–67.10.1007/s10924-008-0104-910.1007/s10924-008-0104-9 ↗
12. Bødker F, Hansen MF, Bender Koch C, Morup S. J. Magn. Magn. Mater. 2000, 221, 32–36.10.1016/S0304-8853(00)00392-910.1016/S0304-8853(00)00392-9 ↗
13. Ajili SH, Ebrahimi NG, Soleimani M. Acta Biomater. 2009, 5, 1519–1530.10.1016/j.actbio.2008.12.01410.1016/j.actbio.2008.12.014 ↗
14. Ajili SH, Ebrahimi NG, Ansari M. Rheol. Acta 2008, 47, 81–87.10.1007/s00397-007-0213-810.1007/s00397-007-0213-8 ↗
15. Mukherjee K, Tribedi P, Chowdhury A, Ray T, Joardar A, Giri S, Sil AK. Biodegradation. 2011, 22, 377–388.10.1007/s10532-010-9409-110.1007/s10532-010-9409-1 ↗
16. Mouritz AP, Gibson AG. Solid Mech. Appl. 2006, 143, 385–401.
17. Shanmugam S, Viswanathan B, Varadarajan TK. Nanoscale Res. Lett. 2007, 2, 175–183.10.1007/s11671-007-9050-z10.1007/s11671-007-9050-z ↗
18. Scott A. Tissue Eng.: Pt. B. 2008, 14, 3–17.10.1089/teb.2007.0133 ↗
19. Storey RF, Wiggins JS, Puckett AD. J. Polym. Sci.: Pt. A: Polym. Chem. 1994, 32, 2345–2363.10.1002/pola.1994.08032121610.1002/pola.1994.080321216 ↗
20. Jabbari E, Khakpour M. Biomaterials. 2000, 21, 2073–2079.10.1016/S0142-9612(00)00135-610.1016/S0142-9612(00)00135-6 ↗
21. Huo L, Li W, Lu L, Cui H, Xi S, Wang J, Shen Y, Lu Z. Chem. Mater. 2000, 12, 790–794.10.1021/cm990690+10.1021/cm990690+ ↗
22. Laurent S, Forge D, Port M, Roch A, Robic C, Elst LV, Muller RN. Chem. Rev. 2008, 108, 2064–2110.10.1021/cr068445e10.1021/cr068445e ↗
23. Arami H, Khandhar A, Liggitt D, Krishnan KM. Chem. Soc. Rev. 2015, 44, 8576–8607.10.1039/C5CS00541H10.1039/C5CS00541H ↗
24. Basuki JS, Jacquemin A, Esser L, Li Y, Boyer C, Davis TP.Polym. Chem. 2014, 5, 2611–2620.10.1039/C3PY01778H10.1039/C3PY01778H ↗
25. Soenen SJ, Parak WJ, Rejman J, Manshian B.Chem. Rev. 2015,115, 2109–2135.10.1021/cr400714j10.1021/cr400714j ↗
26. Seehra MS, Babu VS, Manivannan A, Lynn JW. Phys. Rev. B. 2000, 61, 3513–3518.10.1103/PhysRevB.61.351310.1103/PhysRevB.61.3513 ↗
27. Meng QB, Lee S-I, Nah C, Lee Y-S. Prog. Org. Coat. 2009, 66, 382–386.10.1016/j.porgcoat.2009.08.01610.1016/j.porgcoat.2009.08.016 ↗
28. Yen MS, Chen PY, Tsai HC. J. Appl. Polym. Sci. 2003, 90, 2824–2833.10.1002/app.1296510.1002/app.12965 ↗
29. Zia KM, Bhatti IA, Barikani M, Zuber M, Bhatti HN. Carbohydr. Polym. 2009, 76, 183–187.10.1016/j.carbpol.2008.10.00510.1016/j.carbpol.2008.10.005 ↗
30. Cabrera L, Gutierrez S, Menendez N, Morales MP, Herrasti P. Electrochim. Acta. 2008, 53, 3436–3441.10.1016/j.electacta.2007.12.00610.1016/j.electacta.2007.12.006 ↗
31. Hei S, Jin Y, Zhang F. J. Chem. 2014, 2014, 1–6.10.1155/2014/546956 ↗
32. Zhang L, Wu HB, Xu R, Lou XW. Cryst. Eng. Commun. 2013, 15, 9332–9335.10.1039/c3ce40996a10.1039/c3ce40996a ↗
33. Kazeminezhad I, Mosivand S. Acta. Phys. Pol. A. 2014, 125, 1210–1214.10.12693/APhysPolA.125.121010.12693/APhysPolA.125.1210 ↗
34. Liu JY, Reni L, Wei Q, Wu JL, Liu S, Wang YJ, Li GY. eXPRESS Polym. Lett. 2011, 5, 742–752.10.3144/expresspolymlett.2011.7210.3144/expresspolymlett.2011.72 ↗
35. Jawaid M, Abdul Khalil HPS, Hassan A, Dungani R, Hadiyane A. Compos. Pt. B. 2013, 45, 619–624.10.1016/j.compositesb.2012.04.06810.1016/j.compositesb.2012.04.068 ↗
36. Huang J, Zou JW, Chang PR, Yu JH, Dufresne A. eXPRESS Polym. Lett. 2011, 5, 362–373.10.3144/expresspolymlett.2011.3510.3144/expresspolymlett.2011.35 ↗
37. Tey JN, Soutar AM, Mhailsalkar SG, Yu H, Hew KM. J. Thin Solid Films. 2006, 504, 384−390.10.1016/j.tsf.2005.09.10410.1016/j.tsf.2005.09.104 ↗
38. Yoo HJ, Lee YH, Kwon JY, Kim HD. J. Fibers Polym. 2001, 2, 122−128.10.1007/BF0287532410.1007/BF02875324 ↗
39. Athawale VD, Kulkarni MA. J. Prog. Org. Coat. 2010, 67, 44−54.10.1016/j.porgcoat.2009.09.01510.1016/j.porgcoat.2009.09.015 ↗
40. Khan FN, Manivel P, Prabakaran K, Jin JS, Jeong ED, Kim HJ, Maiyalagan T. Res. Chem. Intermed. 2012, 38, 571–582.10.1007/s11164-011-0372-110.1007/s11164-011-0372-1 ↗
41. Wei X, Viadero Jr RC. Coll. Surf. A: Physicochem. Eng. Asp. 2007, 294, 280–286.10.1016/j.colsurfa.2006.07.06010.1016/j.colsurfa.2006.07.060 ↗
42. Guo Z, Lei K, Li Y, Ng H, Hahn HT. Compos. Sci. Technol. 2008, 68, 1513–1520.10.1016/j.compscitech.2007.10.01810.1016/j.compscitech.2007.10.018 ↗
43. Guo Z, Lee S-E, Kim H, Park S, Hahn HT, Karki AB, Young DP. Acta Mater. 2009, 57, 267–277.10.1016/j.actamat.2008.09.02410.1016/j.actamat.2008.09.024 ↗
44. Tiar Ong H, Muhd Julkapli N, Bee Abd Hamid S, Boondamnoen O, Foong Tai M. J. Magn. Magn. Mater. 2015, 395, 173–179.10.1016/j.jmmm.2015.07.02810.1016/j.jmmm.2015.07.028 ↗
45. Jung J-S, Malkinski L, Lim J-H, Yu M, O’Connor CJ, Lee H-O, Kim E-M. Bull. Kor. Chem. Soc. 2008, 29, 758–760.10.5012/bkcs.2008.29.4.758
46. Shanmugam S, Nakanishi T, Osaka T. J. Electrochem. Soc. 2009, 156, K121–K127.10.1149/1.3125767 ↗