journal article·2019-01-28Open access

Synthesis, electrical properties, and kinetic thermal analysis of polyaniline/ polyvinyl alcohol - magnetite nanocomposites film

Huda AlFannakh, S. S. Arafat, S. S. Ibrahim

Abstract

Abstract Polyaniline-poly vinyl alcohol (PANI-PVA) conducting blends containing 15 wt% aniline were synthesized by in situ polymerization of aniline. Three-phase polymer blended nanocomposites with different contents of magnetite (5, 10 and 15 wt.%) were also synthesized. We measured the current-voltage (I-V) curves for the conducting blend and its magnetite nanocomposite. We also measured their thermal stability, and performed kinetic analysis through thermogravimetric analysis. We observed that the three phase nanocomposites showed enhanced electrical conductivity compared with that of the conductive blend, and no electrical hysteresis. The PVA/PANi blend was more stable above 350 ∘ C and the addition of Fe 3 O 4 enhanced the thermal stability of the conductive blend. The apparent activation energy of the three phase nanocomposites was greater than those of both the pure PVA and PVA/PANi samples. These results suggest that such three phase nanocomposites could be used in a range of applications.
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Research context

OpenAlex topics: Conducting polymers and applications · Advanced Battery Materials and Technologies · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Physics Department, College of Science, King Faisal University (KFU) , KSA, Hofuf , Saudi Arabia

Physics Department, Faculty of Science, Fayoum University , Fayoum , Egypt

Physics Department, Faculty of Science, Cairo University , Cairo , Egypt

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