DataVXACS Energy LettersPaper
journal article·2022-08-12Open access

Manipulating Interfacial Dissolution–Redeposition Dynamics to Resynthesize Electrode Surface Chemistry

Anyang Hu, Yuxin Zhang, Fan Yang, Sooyeon Hwang, Sami Sainio, Dennis Nordlund, Evan Maxey, Qilin Dai, Jing Gu, Luxi Li, Feng Lin

ACS Energy Letters· Volume 7· Issue 8
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Source abstract

Abstract

The solid–liquid electrochemical interface offers a reactive environment for interfacial reactions to tailor electrode surface chemistry under operating conditions. Herein, we demonstrate that the dissolution and redeposition kinetics of transition metal cations, a ubiquitous phenomenon at the electrochemical interface, can be manipulated to regulate the chemical composition and crystal structure of the electrode surface, as well as the overall electrochemical performance. Foreign cations (e.g., Ti4+), either added as electrolyte additives or dissolved from surface coatings, can rapidly participate in the electrode dissolution–redeposition process and facilitate the establishment of the dissolution–redeposition equilibrium. Our work expands the control over the electrochemical reactions at the solid–liquid interface and provides new insights into interfacial studies in electrochemistry and surface science.
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Research context

Energy storage

OpenAlex topics: Advanced battery technologies research · Electrocatalysts for Energy Conversion · Electrochemical Analysis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, United States

Department of Chemistry and Biochemistry, San Diego State University, San Diego, California 92181, United States

Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States

Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States

Microelectronics Research Unit, Faculty of Information Technology and Electrical Engineering University of Oulu, P.O. Box. 4500, 90570 Oulu, Finland

Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States

Department of Chemistry, Physics and Atmospheric Sciences, Jackson State University, Jackson, Mississippi 39217, United States

Funding

Walter Ahlstr?min S??ti? · H2020 Marie Sklodowska-Curie Actions · Division of Chemical, Bioengineering, Environmental, and Transport Systems

References (27)

Show source-provided references
1. 10.1038/s41578-021-00314-y10.1038/s41578-021-00314-y ↗
2. Huggins R. · 2008
3. 10.1039/C6CS00918B10.1039/C6CS00918B ↗
4. 10.1039/D0CS00137F10.1039/D0CS00137F ↗
5. 10.1126/science.abc545410.1126/science.abc5454 ↗
6. 10.1149/1.162734710.1149/1.1627347 ↗
7. 10.1002/adma.20180175110.1002/adma.201801751 ↗
8. 10.1039/C5CP07219K10.1039/C5CP07219K ↗
9. 10.1039/C1CC14764A10.1039/C1CC14764A ↗
10. 10.1039/C3EE42704H10.1039/C3EE42704H ↗
11. 10.1039/c0jm00154f10.1039/c0jm00154f ↗
12. 10.1002/admi.20160056410.1002/admi.201600564 ↗
13. 10.1021/acs.jpclett.5b0172710.1021/acs.jpclett.5b01727 ↗
14. 10.1038/nmat473810.1038/nmat4738 ↗
15. 10.1021/acscatal.8b0103210.1021/acscatal.8b01032 ↗
16. 10.1021/jacs.0c0112310.1021/jacs.0c01123 ↗
17. 10.1021/ja301266w10.1021/ja301266w ↗
18. 10.1021/jacs.7b0026110.1021/jacs.7b00261 ↗
19. 10.1021/jacs.1c0797510.1021/jacs.1c07975 ↗
20. 10.1039/D0TA06612E10.1039/D0TA06612E ↗
21. 10.1021/jacs.7b0447110.1021/jacs.7b04471 ↗
22. 10.1016/0022-0728(90)87385-W10.1016/0022-0728(90)87385-W ↗
23. 10.1103/PhysRevB.69.24510210.1103/PhysRevB.69.245102 ↗
24. 10.1038/s41929-020-0496-z10.1038/s41929-020-0496-z ↗
25. 10.1021/acsami.0c0011110.1021/acsami.0c00111 ↗
26. 10.1039/D0EE02168G10.1039/D0EE02168G ↗
27. 10.1088/0957-4484/20/22/22570110.1088/0957-4484/20/22/225701 ↗