journal article·2022-08-12Open access

Analyzing Production Rate and Carbon Utilization Trade-offs in CO2RR Electrolyzers

Steven A. Hawks, Victoria M. Ehlinger, Thomas Moore, Eric B. Duoss, Victor A. Beck, Adam Z. Weber, Sarah E. Baker

ACS Energy Letters· Volume 7· Issue 8

Abstract

Carbon utilization is a crucially important performance characteristic of CO2 electrolyzers; however, applications of simple and accurate descriptive models to experimental data on this topic are currently lacking. Here, we apply a simple analytical reactor model to parameterize single-pass conversion as a function of feed-gas flow rate and show that it captures a wide body of experimental data in the literature exceptionally well. In doing so, we demonstrate that this simple conceptual approach can characterize progress and capture recent innovations in reactor design. To validate the extracted parameters, we employ a well-established comprehensive model to confirm that the results agree with physical expectations. Finally, we explore the implications of the descriptive model by examining the inherent trade-off between single-pass conversion efficiency and reactor productivity. Understanding such trade-offs is crucially important for advancing this electrolyzer technology toward commercial applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Advanced battery technologies research · Carbon Dioxide Capture Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials Science Division, Lawrence Livermore National Laboratory, Livermore, California 94550, United States

Computational Engineering Division, Lawrence Livermore National Laboratory, Livermore, California 94550, United States

Materials Engineering Division, Lawrence Livermore National Laboratory, Livermore, California 94550, United States

Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

Funding

Lawrence Livermore National Laboratory · TOTAL American Services, Inc.

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