Research progress on properties of cement-based composites incorporating graphene oxide
Source abstract
Abstract
Abstract Graphene oxide (GO) is a two-dimensional derivative of graphene material, with carboxy, hydroxy group functional groups at the middle of the sheets, and oxygen-containing functional groups at sheet edges. It has multiple advantages, such as high strength, hydrophilicity, and strong reactivity. With the development of construction materials, GO has been widely used as a nano-reinforced material in cement-based composites (CBCs). Based on a large amount of relevant literature, the preparation and dispersion behavior of GO-reinforced CBC are summarized. Besides, the impact of GO on the workability, volume stability, mechanical performance, and durability of CBC are discussed. Moreover, the influencing mechanism of GO on the hydration of CBC is expounded. From the findings of this review, the following conclusions can be drawn: the fluidity of CBC will be decreased when GO is evenly dispersed in the cement slurry, which results in a loss of workability of CBC. Meanwhile, the addition of GO improves the volume stability of CBC, while the tensile, compressive, and flexural strengths are all improved to varying degrees. The improvement of GO on the durability of CBC is mainly reflected in the corrosion resistance and permeability resistance. In addition, problems existing in the current research are summarized and future perspectives are put forward. The review work in this article could offer important guidance for further research and implementation of GO-doped CBC in practical engineering.
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Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Recycled Aggregate Concrete Performance
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Yellow River Laboratory, Zhengzhou University , Zhengzhou , 450001 , China
School of Water Conservancy and Civil Engineering, Zhengzhou University , Zhengzhou , 450001 , China
References (100+)
Show source-provided references
1. Wang, L., X. M. Zeng, Y. Li, H. M. Yang, and S. W. Tang. Influences of MgO and PVA fiber on the abrasion and cracking resistance, pore structure and fractal features of hydraulic concrete. Fractal and Fractional, Vol. 6, 2022, id. 674.10.3390/fractalfract6110674 ↗
2. Zhang, T. S., P. Gao, P. H. Gao, J. X. Wei, and Q. J. Yu. Effectiveness of novel and traditional methods to incorporate industrial wastes in cementitious materials-an overview. Resources, Conservation and Recycling, Vol. 74, 2013, pp. 134–143.10.1016/j.resconrec.2013.03.003 ↗
3. Zheng, Y. X., J. B. Zhuo, P. Zhang, and M. Ma. Mechanical properties and meso-microscopic mechanism of basalt fiber-reinforced recycled aggregate concrete. Journal of Cleaner Production, Vol. 370, 2022, id. 133555.10.1016/j.jclepro.2022.133555 ↗
4. Zhang, P., M. H. Wang, X. Han, and Y. X. Zheng. A review on properties of cement-based composites doped with Graphene. Journal of Building Engineering, Vol. 70, 2023, id. 106367.10.1016/j.jobe.2023.106367 ↗
5. Zhang, P., J. Su, J. J. Guo, and S. W. Hu. Influence of carbon nanotube on properties of concrete: A review. Construction and Building Materials, Vol. 369, 2023, id. 130388.10.1016/j.conbuildmat.2023.130388 ↗
6. Wang, L., X. Lu, L. S. Liu, J. Xiao, G. Zhang, F. X. Guo, et al. Influence of MgO on the hydration and shrinkage behavior of low heat Portland cement-based materials via pore structural and fractal analysis. Fractal and Fractional, Vol. 6, 2022, id. 40.10.3390/fractalfract6010040 ↗
7. Zhang, P., S. Y. Wei, J. J. Wu, Y. Zhang, and Y. X. Zheng. Investigation of mechanical properties of PVA fiber-reinforced cementitious composites under the coupling effect of wet-thermal and chloride salt environment. Case Studies in Construction Materials, Vol. 17, 2022, id. e1325.10.1016/j.cscm.2022.e01325 ↗
8. Zhang, P., X. Y. Sun, F. Wang, and J. Wang. Mechanical properties and durability of geopolymer recycled aggregate concrete: A review. Polymers, Vol. 15, 2023, id. 615.10.3390/polym15030615 ↗
9. Chuah, S., Z. Pan, J. G. Sanjayan, C. M. Wang, and W. H. Duan. Nano reinforced cement and concrete composites and new perspective from Graphene Oxide. Construction and Building Materials, Vol. 73, 2014, pp. 113–124.10.1016/j.conbuildmat.2014.09.040 ↗
10. Bautista Gutierrez, K. P., A. L. Herrera May, J. M. Santamaria Lopez, A. Honorato Moreno, and S. A. Zamora Castro. Recent progress in nanomaterials for modern concrete infrastructure: Advantages and challenges. Materials (Basel), Vol. 12, 2019, id. 3548.10.3390/ma12213548 ↗
11. Gladwin Alex, A., A. Kedir, and T. Gebrehiwet Tewele. Review on effects of Graphene Oxide on mechanical and microstructure of cement-based materials. Construction and Building Materials, Vol. 360, 2022, id. 129609.10.1016/j.conbuildmat.2022.129609 ↗
12. Golewski, G. L. and B. Szostak. Strengthening the very early-age structure of cementitious composites with coal fly ash via incorporating a novel nanoadmixture based on C-S-H phase activators. Construction and Building Materials, Vol. 312, 2021, id. 125426.10.1016/j.conbuildmat.2021.125426 ↗
13. Kashif Ur Rehman, S., Z. Ibrahim, S. Memon, M. Aunkor, M. Faisal Javed, K. Mehmood, et al. Influence of Graphene nanosheets on rheology, microstructure, strength development and self-sensing properties of cement based composites. Sustainability, Vol. 10, 2018, id. 822.10.3390/su10030822 ↗
14. Han, Q. Y., P. Zhang, J. J. Wu, Y. T. Jing, D. Zhang, and T. H. Zhang. Comprehensive review of the properties of fly ash-based geopolymer with additive of nano-SiO2. Nanotechnology Reviews (Berlin), Vol. 11, 2022, pp. 1478–1498.10.1515/ntrev-2022-0092 ↗
15. Zhang, X. M., P. Zhang, T. Y. Wang, Y. Zheng, L. H. Qiu, and S. W. Sun. Compressive strength and anti-chloride ion penetration assessment of geopolymer mortar merging PVA fiber and nano-SiO2 using RBF-BP composite neural network. Nanotechnology Reviews (Berlin), Vol. 11, 2022, pp. 1181–1192.10.1515/ntrev-2022-0069 ↗
16. Zhang, P., Z. Gao, J. Wang, J. J. Guo, and T. Y. Wang. Influencing factors analysis and optimized prediction model for rheology and flowability of nano-SiO2 and PVA fiber reinforced alkali-activated composites. Journal of Cleaner Production, Vol. 366, 2022, id. 132988.10.1016/j.jclepro.2022.132988 ↗
17. Zhang, P., S. Y. Wei, Y. X. Zheng, F. Wang, and S. W. Hu. Effect of single and synergistic reinforcement of PVA fiber and nano-SiO2 on workability and compressive strength of geopolymer composites. Polymers, Vol. 14, 2022, id. 3765.10.3390/polym14183765 ↗
18. Zheng, Y. X., J. B. Zhuo, Y. M. Zhang, and P. Zhang. Mechanical properties and microstructure of nano-SiO2 and basalt-fiber-reinforced recycled aggregate concrete. Nanotechnology Reviews (Berlin), Vol. 11, 2022, pp. 2169–2189.10.1515/ntrev-2022-0134 ↗
19. Zhao, Z. F., C. Xiao, B. Fang, Y. J. Lu, T. Shi, Z. G. Zhao, et al. Effect of CNTs and MEA on the creep of face-slab concrete at an early age. Nanotechnology Reviews, Vol. 11, 2022, pp. 2535–2546.10.1515/ntrev-2022-0145 ↗
20. Wang, J. L., S. F. Dong, S. D. Pang, C. S. Zhou, and B. G. Han. Pore structure characteristics of concrete composites with surface-modified carbon nanotubes. Cement and Concrete Composites, Vol. 128, 2022, id. 104453.10.1016/j.cemconcomp.2022.104453 ↗
21. Dong, S. F., D. N. Wang, A. Ashour, B. G. Han, and J. P. Ou. Nickel plated carbon nanotubes reinforcing concrete composites: from nano/micro structures to macro mechanical properties. Composites Part A: Applied Science and Manufacturing, Vol. 141, 2021, id. 106228.10.1016/j.compositesa.2020.106228 ↗
22. Zhang, P., Q. Y. Han, J. J. Wu, Y. Zhang, and T. H. Zhang. Mechanical properties of nano-SiO2 reinforced engineered cementitious composites after exposure to high temperatures. Construction and Building Materials, Vol. 356, 2022, id. 129123.10.1016/j.conbuildmat.2022.129123 ↗
23. Jin, Q. Q., P. Zhang, J. J. Wu, and D. H. Sha. Mechanical properties of nano-SiO2 reinforced geopolymer concrete under the coupling effect of a wet-thermal and chloride salt environment. Polymers, Vol. 14, 2022, id. 2298.10.3390/polym14112298 ↗
24. Zheng, Y. X., Y. H. Zhang, J. B. Zhuo, P. Zhang, and W. X. Kong. Mechanical properties and microstructure of nano-strengthened recycled aggregate concrete. Nanotechnology Reviews, Vol. 11, 2022, pp. 1499–1510.10.1515/ntrev-2022-0077 ↗
25. Zhao, Y. J., Y. M. Liu, T. Shi, Y. Gu, B. M. Zheng, K. Zhang, et al. Study of mechanical properties and early-stage deformation properties of Graphene-modified cement-based materials. Construction and Building Materials, Vol. 257, 2020, id. 119498.10.1016/j.conbuildmat.2020.119498 ↗
26. Kalaitzidou, K., H. Fukushima, and L. T. Drzal. A new compounding method for exfoliated graphite-polypropylene nanocomposites with enhanced flexural properties and lower percolation threshold. Composites Science and Technology, Vol. 67, 2007, pp. 2045–2051.10.1016/j.compscitech.2006.11.014 ↗
27. Shamsaei, E., F. B. de Souza, X. P. Yao, E. Benhelal, A. Akbari, and W. H. Duan. Graphene-based nanosheets for stronger and more durable concrete: A review. Construction and Building Materials, Vol. 183, 2018, pp. 642–660.10.1016/j.conbuildmat.2018.06.201 ↗
28. Lin, Z. Y., B. Wang, and J. W. Min. Review and prospect of Graphene Oxide concrete. Henan Science and Technology, Vol. 40, 2021, pp. 120–122.
29. Guo, B. D., Q. Liu, E. Chen, H. W. Zhu, L. Fang, and J. R. Gong. Controllable n-doping of Graphene. Nano Letters, Vol. 10, 2010, pp. 4975–4980.10.1021/nl103079j ↗
30. Yoshiaki, M. Preparation of intercalation compounds of Graphite Oxide. Carbon, Vol. 45, 2007, pp. 2459–2462.10.1016/j.carbon.2007.06.069 ↗
31. Schniepp, H. C., J. Li, M. J. McAllister, H. Sai, M. Herrera-Alonso, D. H. Adamson, et al. Functionalized single Graphene sheets derived from splitting Graphite Oxide. J Phys Chem B, Vol. 110, 2006, pp. 8535–8539.10.1021/jp060936f ↗
32. Nakajima, T. and Y. Matsuo. Formation process and structure of Graphite Oxide. Carbon, Vol. 32, 1994, pp. 469–475.10.1016/0008-6223(94)90168-6 ↗
33. Marcano, D. C., D. V. Kosynkin, J. M. Berlin, A. Sinitskii, Z. Sun, A. S. Slesarev, et al. Improved synthesis of Graphene Oxide. ACS Nano, Vol. 8, 2010, pp. 4806–4814.10.1021/nn1006368 ↗
34. Shen, J., Y. Hu, M. Shi, X. Lu, C. Qin, C. Li, et al. Fast and facile preparation of Graphene Oxide and reduced Graphene Oxide nanoplatelets. Chemistry of Materials, Vol. 21, 2009, pp. 3514–3520.10.1021/cm901247t ↗
35. Chen, J., B. Yao, C. Li, and G. Shi. An improved Hummers method for eco-friendly synthesis of Graphene Oxide. Carbon, Vol. 64, 2013, pp. 225–229.10.1016/j.carbon.2013.07.055 ↗
36. Wang, Q., G. D. Qi, Y. Wang, H. Y. Zheng, and S. H. Shan. Research progress on the effect of Graphene Oxide on the properties of cement-based composites. New Carbon Materials, Vol. 36, 2021, pp. 729–750.10.1016/S1872-5805(21)60071-9 ↗
37. Zhao, Z. F., T. Q. Qi, W. Zhou, D. Hui, C. Xiao, J. Y. Qi, et al. A review on the properties, reinforcing effects, and commercialization of nanomaterials for cement-based materials. Nanotechnology Reviews (Berlin), Vol. 9, 2020, pp. 303–322.10.1515/ntrev-2020-0023 ↗
38. Zhang, Z. R., J. D. Wu, L. G. Wang, and D. X. Li. Research progress on application of Graphene Oxide in cement matrix composites. Bulletin of the Chinese Ceramic Society, Vol. 36, 2017, pp. 3008–3012.
39. Li, X. Y., A. H. Korayem, C. Y. Li, Y. M. Liu, H. S. He, J. G. Sanjayan, et al. Incorporation of Graphene Oxide and silica fume into cement paste: A study of dispersion and compressive strength. Construction and Building Materials, Vol. 123, 2016, pp. 327–335.10.1016/j.conbuildmat.2016.07.022 ↗
40. Wei, J., Z. Y. Jia, Y. Wang, Y. C. Jiang, Z. Miao, Y. Q. Zhou, et al. Enhanced thermoelectric performance of low carbon cement-based composites by reduced Graphene Oxide. Energy and Buildings, Vol. 250, 2021, id. 111279.10.1016/j.enbuild.2021.111279 ↗
41. Lu, D., X. M. Shi, and J. Zhong. Interfacial nano-engineering by Graphene Oxide to enable better utilization of silica fume in cementitious composite. Journal of Cleaner Production, Vol. 354, 2022, id. 131381.10.1016/j.jclepro.2022.131381 ↗
42. Zhu, L. L. Controllable dispersion of Graphene Oxide and its Impact on structure and properties of cement-based composites. Shaanxi University of Science & Technology, Xi’an City, China, 2018.
43. Zhang, J. Effect of Graphene Oxide on structure and properties of cement-based composite. Shaanxi University of Science & Technology, Xi’an City, China, 2019.
44. Naresh, K. T., V. K. Vishnu, K. M. Hari, and N. P. Venkata. Effect of Graphene Oxide on strength properties of cementitious materials: A review. Materials Today: Proceedings, Vol. 46, 2021, pp. 2157–2160.10.1016/j.matpr.2021.02.637 ↗
45. Xu, Y. D., J. J. Zeng, W. Chen, J. H. Mao, J. S. Shen, and D. Y. Hu. A state-of-the-art review on Graphene Oxide reinforced cement based composites. Materials Reports, Vol. 31, 2017, pp. 150–155.
46. Szostak, B. and G. L. Golewski. Rheology of cement pastes with siliceous fly ash and the CSH nano-admixture. Materials (Basel), Vol. 14, 2021, id. 3640.10.3390/ma14133640 ↗
47. Zeng, J. Q., Y. D. Xu, Z. H. Pan, D. Y. Hu, and P. Wu. Preparation and mechanism of Graphite Oxide reinforced cement based composites. Journal of Jiangsu University of Science and Technology(Natural Science Edition), Vol. 33, 2019, pp. 126–130.
48. Wang, Q., J. Wang, C. X. Lu, B. W. Lu, K. Zhang, and C. Z. Li. Influence of Graphene Oxide additions on the microstructure and mechanical strength of cement. New Carbon Materials, Vol. 30, 2015, pp. 349–356.10.1016/S1872-5805(15)60194-9 ↗
49. Lu, L. L. and D. Ouyang. Properties of cement mortar and ultra-high strength concrete incorporating Graphene Oxide nanosheets. Nanomaterials, Vol. 7, 2017, id. 187.10.3390/nano7070187 ↗
50. Gao, D. G. and Y. J. Ma. Preparation and properties of copolymer of Graphene Oxide and monomers of polycarboxylate superplasticizer. Fine Chemicals, Vol. 32, 2015, pp. 103–107, 120.
51. Cui, X. Y. Effect of Graphene Oxide on properies and mechanism of cement fly ash system. Beijing University of Civil Engineering and Architecture, 2018.
52. Shang, Y., D. Zhang, C. Yang, Y. Y. Liu, and Y. Liu. Effect of Graphene Oxide on the rheological properties of cement pastes. Construction and Building Materials, Vol. 96, 2015, pp. 20–28.10.1016/j.conbuildmat.2015.07.181 ↗
53. Lv, S. H., Y. Y. Cui, T. Sun, H. F. Zhao, J. J. Liu, and H. D. Ding. Effects of Graphene Oxide on fluidity of cement paste and structure and properties of hardened cement paste. Journal of Functional Materials, 2015, Vol. 4, pp. 4051–4056.
54. Liu, C. J., X. C. Huang, Y. Y. Wu, X. W. Deng, J. Liu, Z. L. Zheng, et al. Review on the research progress of cement-based and geopolymer materials modified by Graphene and Graphene Oxide. Nanotechology Reviews, Vol. 9, 2020, pp. 155–169.10.1515/ntrev-2020-0014 ↗
55. Zhan, J. J. and C. L. Liu. The concrete physical volume stability analysis. Journal of Liaoning Provincial College of Communications, Vol. 8, 2006, pp. 39–40.
56. Zhou, X. Study on mechanical properties and shrinkage and creep of high performance Graphene Oxide concrete. Chongqing Jiaotong University, Chongqing City, China, 2019.
57. Radman, A. and N. Joorabchi. Property assessment of concretes with Graphene Oxide mixed cement. IOP Conference Series: Materials Science and Engineering, Vol. 652, 2019, id. 12043.10.1088/1757-899X/652/1/012043 ↗
58. Zheng, H. J. High temperature performance of graphite modified concrete. Bulletin of the Chinese Ceramic Society, Vol. 39, 2020, pp. 3851–3857.
59. Wang, Y., Y. D. Xu, J. Q. Zeng, Z. H. Pan, and M. M. Li. Influence of Graphene Oxide on autogenous shrinkage of cement-based composites. Journal of Functional Materials, Vol. 51, 2020, pp. 3108–3113.
60. Cheng, Z. H., S. Yang, and X. Y. Yuan. Research progress of cement-based materials blended with Graphene and its derivatives. Acta Materiae Compositae Sinica, Vol. 38, 2021, pp. 339–360.
61. Lv, S. H., T. Sun, J. J. Liu, Y. J. Ma, and C. C. Qiu. Toughening effect and mechanism of Graphene Oxide nanosheets on cement matrix composites. Acta Materiae Compositae Sinica, Vol. 31, 2014, pp. 644–652.
62. Lv, S. H., L. Sun, J. Zhang, H. Y. Hu, Y. Lei, and Y. G. Hou. High/ultra-high performence Graphene Oxide/cement-based composites with large-scale, ordered and compact flower-like microstructures. Materials Reports, Vol. 31, 2017, pp. 78–84.
63. Jiang, X. F. Study on hydration and mechanical properties of Graphene nanoplatelets/Graphene Oxide reinforced cement-based composites. Jiangsu University, Nanjing City, China, 2020.
64. Zeng, J. J., Z. Y. Gao, and D. Ruan. Effect of Graphene Oxide on microstructure and mechanical properties of concrete. Journal of Functional Materials, Vol. 52, 2021, pp. 12123–12128.
65. Gui, C., Z. F. Xu, Y. J. Jiang, and S. H. Li. Preparation of Graphene Oxide/recycled cement-based composite materials. Acta Materiae Compositae Sinica, Vol. 38, 2021, pp. 1526–1534.
66. Wang, Z. M. and H. L. Zhang. Research on mechanical properties of cement-based composites reinforced with nano Graphene Oxide. Industrial Construction, Vol. 51, 2021, pp. 153–157.
67. Zhang, P., C. Wang, Z. Gao, and F. Wang. A review on fracture properties of steel fiber reinforced concrete. Journal of Building Engineering, Vol. 67, 2023, id. 105975.10.1016/j.jobe.2023.105975 ↗
68. LI, X. and S. R. Luo. Fracture properties of Graphene Oxide reinforced cement composites. Acta Materiae Compositae Sinica, Vol. 38, 2021, pp. 612–621.
69. Wang, M. G. Application of Graphene Oxide concrete in cement concrete pavement. Technology of Highway and Transport, Vol. 35, 2019, pp. 43–46.
70. Murthy, A. R., P. Ganesh, S. S. Kumar, and N. R. Iyer. Fracture energy and tension softening relation for nano-modified concrete. Structural Engineering and Mechanics, Vol. 54, 2015, pp. 1201–1216.10.12989/sem.2015.54.6.1201 ↗
71. Murthy, A. R. and P. Ganesh. Effect of steel fibres and nano silica on fracture properties of medium strength concrete. Advances in Concrete Construction, Vol. 7, 2019, pp. 143–150.
72. He, Q. and H. Deng. Effect of Graphene Oxide size on cement-based composites. Bulletin of the Chinese Ceramic Society, Vol. 38, 2019, pp. 3145–3149.
73. Wang, M. G. Study on Graphene Oxide to improve performance of cement-based composites. Technology of Highway and Transport, Vol. 36, 2020, pp. 37–41.
74. Shi, X. X. and G. J. Sun. Effect of Graphene Oxide on mechanical properties of cement based materials. Non-Metallic Mines, Vol. 44, 2021, pp. 47–50.
75. Lu, Q., Y. Y. Wu, and G. R. Zhan. Study on the effect of Graphene Oxide on the performance of ultra-high-performance concrete. Journal of Foshan University (Natural Science Edition), Vol. 39, 2021, pp. 64–67.
76. Li, J. P., L. Qin, P. Zhao, and X. S. Fan. Acoustic emission detection of Graphene Oxide concrete. Nondestructive Testing, Vol. 41, 2019, pp. 6–10.
77. Balasubramaniam, T., M. Karthick, and M. Arun. Performance assessment of concrete incorporating recycled coarse aggregates and Graphene Oxide. IOP Conference Series: Materials Science and Engineering, Vol. 1059, 2021, id. 12069.10.1088/1757-899X/1059/1/012069 ↗
78. Liu, C. J., F. L. Chen, Y. Y. Wu, Z. L. Zheng, J. W. Yang, B. Yang, et al. Research progress on individual effect of Graphene Oxide in cement-based materials and its synergistic effect with other nanomaterials. Nanotechnology Reviews (Berlin), Vol. 10, 2021, pp. 1208–1235.10.1515/ntrev-2021-0080 ↗
79. Lu, Z. Y., D. S. Hou, H. Y. Ma, T. Y. Fan, and Z. J. Li. Effects of Graphene Oxide on the properties and microstructures of the magnesium potassium phosphate cement paste. Construction and Building Materials, Vol. 119, 2016, pp. 107–112.10.1016/j.conbuildmat.2016.05.060 ↗
80. Du, Y. H., J. Yang, B. Skariah Thomas, L. H. Li, H. Y. Li, and S. Nazar. Hybrid Graphene Oxide/carbon nanotubes reinforced cement paste: an investigation on hybrid ratio. Construction and Building Materials, Vol. 261, 2020, id. 119815.10.1016/j.conbuildmat.2020.119815 ↗
81. Du, Y. H., J. Yang, B. Skariah Thomas, L. H. Li, H. Y. Li, W. Mohamed Shaban, et al. Influence of hybrid Graphene Oxide/carbon nanotubes on the mechanical properties and microstructure of magnesium potassium phosphate cement paste. Construction and Building Materials, Vol. 260, 2020, id. 120449.10.1016/j.conbuildmat.2020.120449 ↗
82. Liu, W. J., L. R. Gu, H. Xiong, and H. M. Wu. Research on the toughening effect of Graphene Oxide on concrete composites. Journal of Functional Materials, Vol. 52, 2021, pp. 12216–12220.
83. Gong, K., Z. Pan, A. H. Korayem, L. Qiu, D. Li, F. Collins, et al. Reinforcing effects of Graphene Oxide on portland cement paste. Journal of Materials in Civil Engineering, Vol. 27, 2015, id. A4014010.10.1061/(ASCE)MT.1943-5533.0001125 ↗
84. Liu, Y. S., M. J. Jia, C. Z. Song, S. Lu, H. Wang, G. H. Zhang, et al. Enhancing ultra-early strength of sulphoaluminate cement-based materials by incorporating Graphene Oxide. Nanotechnology Reviews (Berlin), Vol. 9, 2020, pp. 17–27.10.1515/ntrev-2020-0002 ↗
85. Lu, D., X. M. Shi, and J. Zhong. Nano-engineering the interfacial transition zone in cement composites with Graphene Oxide. Construction and Building Materials, Vol. 356, 2022, id. 129284.10.1016/j.conbuildmat.2022.129284 ↗
86. Liu, C. J., X. C. Huang, Y. Y. Wu, X. W. Deng, Z. L. Zheng, Z. Xu, et al. Advance on the dispersion treatment of Graphene Oxide and the Graphene Oxide modified cement-based materials. Nanotechnology Reviews, Vol. 10, 2021, pp. 34–49.10.1515/ntrev-2021-0003 ↗
87. Babak, F., H. Abolfazl, R. Alimorad, and G. Parviz. Preparation and mechanical properties of Graphene Oxide: Cement nanocomposites. Scientific World Journal, Vol. 2014, 2014, id. 276323.10.1155/2014/276323 ↗
88. Lv, S. H., Y. J. Ma, C. C. Qiu, and H. B. Ju. Study on reinforcing and toughening of Graphene Oxide to cement-based composites. Journal of Functional Materials, Vol. 44, 2013, pp. 2227–2231.
89. Zhao, L., X. L. Guo, C. Ge, Q. Li, L. P. Guo, X. Shu, et al. Mechanical behavior and toughening mechanism of polycarboxylate superplasticizer modified Graphene Oxide reinforced cement composites. Composites Part B: Engineering, Vol. 113, 2017, pp. 308–316.10.1016/j.compositesb.2017.01.056 ↗
90. Zhao, L., X. L. Guo, C. Ge, Q. Li, L. P. Guo, X. Shu, et al. Investigation of the effectiveness of PC@GO on the reinforcement for cement composites. Construction and Building Materials, Vol. 113, 2016, pp. 470–478.10.1016/j.conbuildmat.2016.03.090 ↗
91. Zhao, H. F., S. H. Lv, and L. J. Deng. Mechanism of reinforcing and toughening cement-based composites by Graphene. Journal of Shaanxi University of Science & Technology, Vol. 34, 2016, pp. 60–64.
92. Lv, S. H., J. Zhang, L. L. Zhu, and C. M. Jia. Regulation of Graphene Oxide on microstructure of cement composites and its impact on compressive and flexural strength. CIESC Journal, Vol. 68, 2017, pp. 2585–2595.
93. Ding, H. D. Preparation of Graphene Oxide composite and its reinforcing and toughening on cement-based materials and polyurethane coating. Shaanxi University of Science & Technology, Xi’an City, China, 2015.
94. Li, Y. Experimental study and numerical simulation of calcium dissolution in cement-based materials. Southeast University, Nanjing City, China, 2012.
95. Liu, R. Research on impermeability of nano-modified cement-based materials and its mechanism. Harbin Institute of Technology, Harbin City, China, 2020.
96. Lin, L. Study on properties of Graphene Oxide/carbon nanotubes cementitious composites. Hunan University, Changsha City, China, 2018.
97. Zhang, P., W. S. Wang, Y. Lv, Z. Gao, and S. Y. Dai. Effect of polymer coatings on the permeability and chloride ion penetration resistances of nano-particles and fibers-modified cementitious composites. Polymers, Vol. 14, 2022, id. 3258.10.3390/polym14163258 ↗
98. Zhang, P., W. S. Wang, Y. J. Lv, K. X. Wang, and S. Y. Dai. Effect of polymer coatings on the freezing-thawing and carbonation resistances of nano-SiO2 and polyvinyl alcohol fiber-reinforced cementitious composites. Journal of Materials Research and Technology, Vol. 21, 2022, pp. 69–83.10.1016/j.jmrt.2022.08.167 ↗
99. Du, T. Effect of Graphene Oxide on properties of cement-based composite. Harbin Institute of Technology, Harbin City, China, 2014.
100. Gong, J. Q. and L. Lin. Study on frost resistance of GO/CNTs cementitious composites. Bulletin of the Chinese Ceramic Society, Vol. 37, 2018, pp. 3410–3415.