Recent Advances in High-Entropy NASICON-Type Polyanionic Cathode Materials for Sodium-Ion Batteries
Source abstract
Abstract
NASICON-type polyanionic compounds (NTPCs) have emerged as a notable class of cathode materials for sodium-ion batteries (SIBs), featuring distinct structural integrity, tunable redox potentials, and favorable thermodynamic stability. Nevertheless, their practical application is impeded by low electronic conductivity, sluggish Na + diffusion kinetics, substantial volume changes, interfacial instability, and restricted theoretical capacity. Fortunately, the emerging high-entropy strategy in the field of energy storage offers a transformative pathway to overcome the bottlenecks of NTPCs. This review elucidates the fundamental concepts underlying high-entropy materials and includes an overview of the structural characteristics, persistent challenges, and conventional modification strategies associated with typical NTPCs. Subsequently, it comprehensively surveys the latest research progress on various high-entropy NTPC systems, including phosphates, fluorophosphates, and mixed-polyanion types, with particular emphasis on their performance enhancement mechanisms. Finally, future research directions are outlined to guide the rational design of high-performance high-entropy NTPC cathodes and accelerate the commercialization of SIBs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Henan Engineering Technology Research Center of Electrochemical Energy Storage, Henan Distinguished Foreign Scientists Workgroup in Electrochemical Energy Storage, School of Chemistry and Chemical Engineering
Henan University of Technology
Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City
School of Environmental Engineering
Faculty of Science and Engineering, Manchester Metropolitan University, Chester Street, M1 5GD Manchester, United Kingdom
State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering
Central South University
Funding
Natural Science Foundation of Henan Province · Key Scientific Research Project of Colleges and Universities in Henan Province · China Postdoctoral Science Foundation · Science and Technology Innovation Talents in Universities of Henan Province · National Natural Science Foundation of China · Henan University of Technology · Henan Distinguished Foreign Scientists Workgroup in Electrochemical Energy Storage, China
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