A Nature-Inspired Solution for Water Management in a Zero-Gap CO₂ Electrolyzer

High Resolution Image Download MS PowerPoint Slide Electroreduction of carbon dioxide (CO 2 RR) holds great promise as a CO 2 emission mitigation strategy while producing valuable chemicals. This study draws inspiration from desert-dwelling lizards to design a flow-field that increases the performance of the CO 2 RR in a zero-gap CO 2 electrolyzer. It achieves a CO partial current density of 165.5 mA cm –2 at 200 mA cm –2, surpassing those of conventional parallel and serpentine flow-field designs. Unlike more complex strategies that can only partially prevent water flooding or salt precipitation, our approach achieves both, solely by modifying the cathodic flow-field, while using commercial electrocatalysts, membranes, and standard operating conditions. When doubling the cell size, the lizard-inspired serpentine flow-field significantly boosts CO production: CO selectivity is 46% and 97% higher than for a conventional serpentine flow-field at 350 mA cm –2 and 400 mA cm –2, respectively. Thus, lizard-inspired flow-field technology could provide a step-change in stable, scalable CO 2 RR, even using commercially available components for the use of CO 2 electrolyzers.