Halide Solid-State Electrolytes for All-Solid-State Sodium Batteries: Progress and Perspectives
Source abstract
Abstract
Halide solid-state electrolytes (HSSEs) have recently emerged as promising candidates for all-solid-state sodium batteries (ASSSBs) due to their high ionic conductivity, wide electrochemical stability window, and good compatibility with high-voltage cathode materials. Here, we comprehensively summarize the latest progress in sodium-ion HSSEs, with a focus on their phase structure–property relationships, synthesis methodologies, stability mechanisms, and practical applications. Additionally, we critically analyze the (electro)chemical stability of HSSEs at both cathode and anode interfaces along with key modification strategies. Finally, we present key future research directions to advance HSSE for next-generation ASSSBs. This review aims to provide fundamental insights and practical guidelines for developing high-performance HSSEs toward next-generation ASSSBs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
CAS Key Laboratory of Green Process and Engineering
Institute of Process Engineering, Chinese Academy of Sciences
School of Chemical Engineering
University of Chinese Academy of Sciences
Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics
Institute of Physics, Chinese Academy of Sciences
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry
Xinjiang University
Funding
Ministry of Science and Technology of the People's Republic of China · Chinese Academy of Sciences · Jiangsu Provincial Carbon Peak and Neutrality Innovation Program (Industry Tackling on Prospect and Key Technology)
References (92)
Show source-provided references
1. 10.1038/s41578-021-00324-w10.1038/s41578-021-00324-w ↗
2. 10.1021/acsenergylett.4c0323010.1021/acsenergylett.4c03230 ↗
3. 10.1002/adfm.20230437110.1002/adfm.202304371 ↗
4. 10.1038/s41467-022-30517-y10.1038/s41467-022-30517-y ↗
5. 10.1039/D2CS01029A10.1039/D2CS01029A ↗
6. 10.1038/s41565-020-0657-x10.1038/s41565-020-0657-x ↗
7. 10.1016/j.joule.2018.07.02810.1016/j.joule.2018.07.028 ↗
8. 10.1002/idm2.1204410.1002/idm2.12044 ↗
9. 10.1002/bte2.2022005110.1002/bte2.20220051 ↗
10. 10.1021/acs.chemmater.3c0298810.1021/acs.chemmater.3c02988 ↗
11. 10.1016/j.electacta.2016.11.17710.1016/j.electacta.2016.11.177 ↗
12. 10.1002/adfm.20200144410.1002/adfm.202001444 ↗
13. 10.1038/s43246-024-00482-810.1038/s43246-024-00482-8 ↗
14. 10.1021/acsenergylett.8b0094810.1021/acsenergylett.8b00948 ↗
15. 10.1016/j.eng.2021.04.02810.1016/j.eng.2021.04.028 ↗
16. 10.1021/acsenergylett.0c0143210.1021/acsenergylett.0c01432 ↗
17. 10.1002/aenm.20160119610.1002/aenm.201601196 ↗
18. 10.1002/aenm.20190289910.1002/aenm.201902899 ↗
19. 10.1038/s41578-019-0157-510.1038/s41578-019-0157-5 ↗
20. 10.1021/acsenergylett.1c0242810.1021/acsenergylett.1c02428 ↗
21. 10.1039/C9EE03828K10.1039/C9EE03828K ↗
22. 10.1021/acsenergylett.2c0043810.1021/acsenergylett.2c00438 ↗
23. 10.1126/sciadv.adc951610.1126/sciadv.adc9516 ↗
24. 10.1021/ja01367a00610.1021/ja01367a006 ↗
25. 10.1149/1.241156010.1149/1.2411560 ↗
26. 10.1149/1.211561110.1149/1.2115611 ↗
27. 10.1016/0167-2738(88)90370-010.1016/0167-2738(88)90370-0 ↗
28. 10.1016/0022-3697(81)90142-610.1016/0022-3697(81)90142-6 ↗
29. 10.1002/zaac.1995621032110.1002/zaac.19956210321 ↗
30. 10.1002/zaac.1997623090510.1002/zaac.19976230905 ↗
31. 10.1016/j.ssi.2008.02.01210.1016/j.ssi.2008.02.012 ↗
32. 10.1002/adma.20180307510.1002/adma.201803075 ↗
33. 10.1021/acssuschemeng.9b0555710.1021/acssuschemeng.9b05557 ↗
34. 10.1021/acsenergylett.9b0259910.1021/acsenergylett.9b02599 ↗
35. 10.1021/acsmaterialslett.1c0014210.1021/acsmaterialslett.1c00142 ↗
36. 10.1021/acs.chemmater.1c0134810.1021/acs.chemmater.1c01348 ↗
37. 10.1021/acsenergylett.0c0169010.1021/acsenergylett.0c01690 ↗
38. 10.1002/smtd.20210100210.1002/smtd.202101002 ↗
39. 10.1039/C9EE02311A10.1039/C9EE02311A ↗
40. 10.1002/ange.20190980510.1002/ange.201909805 ↗
41. 10.1126/sciadv.abh189610.1126/sciadv.abh1896 ↗
42. 10.1002/anie.20240137310.1002/anie.202401373 ↗
43. 10.1002/batt.20240000510.1002/batt.202400005 ↗
44. 10.1039/D0EE01569E10.1039/D0EE01569E ↗
45. 10.1021/acsaem.0c0187010.1021/acsaem.0c01870 ↗
46. 10.1021/jacs.0c0013410.1021/jacs.0c00134 ↗
47. 10.1038/s41467-021-21488-710.1038/s41467-021-21488-7 ↗
48. 10.1021/acsenergylett.2c0151410.1021/acsenergylett.2c01514 ↗
49. 10.1021/acs.jpclett.0c0001010.1021/acs.jpclett.0c00010 ↗
50. 10.1021/acsmaterialslett.3c0011910.1021/acsmaterialslett.3c00119 ↗
51. 10.1016/j.ensm.2021.01.02610.1016/j.ensm.2021.01.026 ↗
52. 10.1039/D2TA05823E10.1039/D2TA05823E ↗
53. 10.1016/j.ensm.2023.10301610.1016/j.ensm.2023.103016 ↗
54. 10.1039/D1TA08086E10.1039/D1TA08086E ↗
55. 10.1038/s41467-024-48712-410.1038/s41467-024-48712-4 ↗
56. 10.1038/s41560-023-01356-y10.1038/s41560-023-01356-y ↗
57. 10.1002/anie.20231418110.1002/anie.202314181 ↗
58. 10.1038/s41467-025-61738-610.1038/s41467-025-61738-6 ↗
59. 10.1039/D2TA05158C10.1039/D2TA05158C ↗
60. 10.1021/acs.chemmater.2c0196610.1021/acs.chemmater.2c01966 ↗
61. 10.1039/D1TA07050A10.1039/D1TA07050A ↗
62. 10.1016/j.matt.2023.12.01710.1016/j.matt.2023.12.017 ↗
63. 10.1002/adma.20230801210.1002/adma.202308012 ↗
64. 10.1002/smll.20240019510.1002/smll.202400195 ↗
65. 10.5796/electrochemistry.23-0005410.5796/electrochemistry.23-00054 ↗
66. 10.1021/acsmaterialslett.4c0031510.1021/acsmaterialslett.4c00315 ↗
67. 10.1016/j.matt.2023.12.02810.1016/j.matt.2023.12.028 ↗
68. 10.1002/aenm.20240209110.1002/aenm.202402091 ↗
69. 10.1021/acsenergylett.4c0049010.1021/acsenergylett.4c00490 ↗
70. 10.1038/s41467-023-38037-z10.1038/s41467-023-38037-z ↗
71. 10.1038/s41563-024-02011-x10.1038/s41563-024-02011-x ↗
72. 10.1002/anie.20191214510.1002/anie.201912145 ↗
73. 10.1002/anie.20241697910.1002/anie.202416979 ↗
74. 10.1021/acsenergylett.4c0185510.1021/acsenergylett.4c01855 ↗
75. 10.1038/s41467-025-58113-w10.1038/s41467-025-58113-w ↗
76. 10.1021/jacs.4c1809010.1021/jacs.4c18090 ↗
77. 10.1002/anie.20242550310.1002/anie.202425503 ↗
78. 10.1002/aenm.20250091310.1002/aenm.202500913 ↗
79. 10.1002/adma.20250310710.1002/adma.202503107 ↗
80. 10.1002/advs.20250722410.1002/advs.202507224 ↗
81. 10.1002/aenm.20250406710.1002/aenm.202504067 ↗
82. 10.1021/acscentsci.6b0027710.1021/acscentsci.6b00277 ↗
83. 10.1088/0953-2048/23/6/06501510.1088/0953-2048/23/6/065015 ↗
84. 10.1016/j.matt.2021.04.01610.1016/j.matt.2021.04.016 ↗
85. 10.1002/aenm.20200341710.1002/aenm.202003417 ↗
86. 10.1002/anie.20200762110.1002/anie.202007621 ↗
87. 10.1016/j.chempr.2023.06.00210.1016/j.chempr.2023.06.002 ↗
88. 10.1002/anie.20220340910.1002/anie.202203409 ↗
89. 10.1002/anie.20230643310.1002/anie.202306433 ↗
90. 10.1002/anie.20241584710.1002/anie.202415847 ↗
91. 10.1002/aenm.20250304710.1002/aenm.202503047 ↗
92. 10.1038/s41560-024-01569-910.1038/s41560-024-01569-9 ↗