Chalcocarbogels as High-Capacity and Cycle-Stable Electrode Materials for Lithium and Sodium Ion Batteries

Taohedul Islam; Mengya Li; Alicia Blanton; Kathryn A. Pitton; Keerthan R. Rao; Sahar Bayat; Kamila M. Wiaderek; Misganaw Adigo Weret; Subrata C Roy; Renfei Feng; Dien Li; Robiul Alam; Jing Nie; Oluwaseun Oketola; Avijit Pramanik; Beth S. Guiton; Chad Risko; Ilias Belharouak; Ruhul Amin; Saiful M. Islam

doi:10.1021/acsenergylett.3c02112

journal article·2024-01-12Open access

Chalcocarbogels as High-Capacity and Cycle-Stable Electrode Materials for Lithium and Sodium Ion Batteries

Taohedul Islam, Mengya Li, Alicia Blanton, Kathryn A. Pitton, Keerthan R. Rao, Sahar Bayat, Kamila M. Wiaderek, Misganaw Adigo Weret, Subrata C Roy, Renfei Feng, Dien Li, Robiul Alam, Jing Nie, Oluwaseun Oketola, Avijit Pramanik, Beth S. Guiton, Chad Risko, Ilias Belharouak, Ruhul Amin, Saiful M. Islam

ACS Energy Letters· Volume 9· Issue 1

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Source abstract

Abstract

The low capacities of commercial Li ion batteries and cycle instabilities of amorphous metal sulfide based batteries impose constraints on their utilization for large-scale energy storage. We report here the acid-free, room-temperature (RT), and solution-based synthesis of a chalcogenide–carbonaceous hybrid aerogel, termed as “chalcocarbogel”, comprising molybdenum sulfide (MoS x ) and graphene oxide (GO). The chalcocarbogel is a nanoparticle-aggregated, porous, amorphous gel consisting of Mo 3 S 13 and Mo 2 S 12 -like structures as determined by synchrotron X-ray PDF, XANES, and EXAFS. The MoS x -GO chalcocarbogel demonstrates high specific capacities of ∼1215 and ∼807 mAh g –1 for Li/MoS x -GO and Na/MoS x -GO cells, respectively, for a 50 mAg –1 discharge rate during the first cycle. After the activation cycles, the MoS x -GO chalcocarbogel stabilizes, maintaining high specific capacities of approximately ∼700 mAh g –1 for Li/MoS x -GO and ∼473 mAh g –1 for Na/MoS x -GO cells, while continuously cycling. The MoS x -GO aerogel reported here serves as a promising platform to develop chalcocarbogels for applications spanning both Li and Na ion batteries.

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Research context

Energy storage Nanomaterials

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Physics, and Atmospheric Sciences, Jackson State University, Jackson, Mississippi 39217, United States

Electrification and Energy Infrastructures Division, Oak Ridge National Laboratory, Hardin Valley Campus, Knoxville, Tennessee 37830, United States

Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, United States

Center for Applied Energy Research, University of Kentucky, Lexington, Kentucky 40511, United States

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States

Canadian Light Source, Saskatoon, Saskatchewan S7N 2V3, Canada

Savannah River National Laboratory, Aiken, South Carolina 29808, United States

Funding

Division of Chemistry · Office of Experimental Program to Stimulate Competitive Research · U.S. Department of Energy · Division of Equity for Excellence in STEM · College of Arts and Sciences, University of Kentucky

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