SYNTHESIS AND PHYSICOCHEMICAL STUDY OF GUM ARABIC SULFATES

Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041, Russia; ALEKSANDR S. KAZACHENKO; FERIDE AKMAN; Vocational School of Food, Agriculture and Livestock, University of Bingöl, Bingöl 12000, Turkey; UTKIRJON HOLIKULOV; Department of Optics and Spectroscopy, Samarkand State University, 15 University Blvd., Samarkand 140104, Uzbekistan; YAROSLAVA BEREZHNAYA; Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia; NOUREDDINE ISSAOUI; Laboratory of Quantum and Statistical Physics, Faculty of Sciences, University Monastir, 5079, Tunisia; ANNA S. KAZACHENKO; Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041, Russia; OMAR M. AL-DOSSARY; Department of Physics and Astronomy, College of Science, King Saud University, PO Box 2455, Riyadh, 11451 Saudi Arabia; OLGA FETISOVA; Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia; SVETLANA NOVIKOVA; Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia

doi:10.35812/cellulosechemtechnol.2025.59.02

journal article·2025-03-10Open access

SYNTHESIS AND PHYSICOCHEMICAL STUDY OF GUM ARABIC SULFATES

Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041, Russia, ALEKSANDR S. KAZACHENKO, FERIDE AKMAN, Vocational School of Food, Agriculture and Livestock, University of Bingöl, Bingöl 12000, Turkey, UTKIRJON HOLIKULOV, Department of Optics and Spectroscopy, Samarkand State University, 15 University Blvd., Samarkand 140104, Uzbekistan, YAROSLAVA BEREZHNAYA, Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia, NOUREDDINE ISSAOUI, Laboratory of Quantum and Statistical Physics, Faculty of Sciences, University Monastir, 5079, Tunisia, ANNA S. KAZACHENKO, Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041, Russia, OMAR M. AL-DOSSARY, Department of Physics and Astronomy, College of Science, King Saud University, PO Box 2455, Riyadh, 11451 Saudi Arabia, OLGA FETISOVA, Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia, SVETLANA NOVIKOVA, Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk 660036, Russia

Cellulose Chemistry and Technology· Volume 59· Issue 1-2

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Abstract

Polysaccharide sulfates have many valuable types of biological activity, such as anticoagulant, hypolipidemic, antithrombotic, etc. The biological activity of sulfated polysaccharides depends on various physicochemical characteristics. In this work, the synthesis and physicochemical characteristics of gum arabic sulfates were studied. Sulfation of gum arabic was carried out with sulfamic acid in the presence of urea with varying ratios of the sulfating complex. The influence of process duration and temperature on the sulfur content in gum arabic sulfates was assessed. The original and sulfated gum arabic was studied using a complex of physicochemical methods: FTIR, XRD, thermal and elemental analysis and DFT. The introduction of a sulfate group into the gum arabic macromolecule was proven by FTIR spectroscopy by the appearance of corresponding absorption bands. According to thermal analysis, during the sulfation process, the thermal stability of gum arabic decreases due to the formation of low-stable sulfuric acid ester groups.

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Polymers

OpenAlex topics: Polysaccharides Composition and Applications · Polysaccharides and Plant Cell Walls

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