DataVXACS Energy LettersPaper
journal article·2023-02-10

Recyclable and Ultrafast Fabrication of Zinc Oxide Interface Layer Enabling Highly Reversible Dendrite-Free Zn Anode

Chenhui Ma, Konghua Yang, Shibo Zhao, Yu Xie, Chunbao Liu, Nan Chen, Chunzhong Wang, Deping Wang, Dong Zhang, Ze Xiang Shen, Fei Du

ACS Energy Letters· Volume 8· Issue 2
Publisher page
Source abstract

Abstract

The surface coating is effective in suppressing Zn dendrite and side reactions, while the existing processing methods employ complex procedures and expensive equipment. Here, we develop an I 2 -assisted processing method to in situ fabricate the ZnO interface layer on the Zn anode (denoted as IAZO). This strategy features the sustainability that the raw materials, I 2, could be reused with a recovery ratio of 67.25% and rapid processing time that only takes 5 min. The IAZO anode achieves an extraordinary cycle life of over 3100 h and a high depth of discharge of 52%, much better than the original Zn anode (less than 220 h and 1.7%). Density functional theory calculations and COMSOL simulation reveal that the IAZO anode has a high binding energy with Zn 2+, which contributes to the uniform distribution of the electric field and Zn 2+ flux.
Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advanced battery technologies research · Perovskite Materials and Applications · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), State Key Laboratory of Superhard Materials, Jilin Key Engineering Laboratory of New Energy Materials and Technologies, College of Physics, Jilin University, Changchun130012, PR China

School of Mechanical and Aerospace Engineering, Jilin University, Changchun130012, PR China

China FAW Group Co. Ltd., No.1, Xinhongqi Street, Changchun130012, PR China

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore637371, Singapore

Funding

Central University Basic Research Fund of China · Department of Science and Technology of Jilin Province · National Natural Science Foundation of China

References (43)

Show source-provided references
1. 10.1021/acsenergylett.0c0237110.1021/acsenergylett.0c02371 ↗
2. 10.1016/j.jpowsour.2022.23112210.1016/j.jpowsour.2022.231122 ↗
3. 10.1007/s40820-021-00764-710.1007/s40820-021-00764-7 ↗
4. 10.1021/acsenergylett.2c0012410.1021/acsenergylett.2c00124 ↗
5. 10.1021/acsenergylett.2c0115210.1021/acsenergylett.2c01152 ↗
6. 10.1039/D2EE00209D10.1039/D2EE00209D ↗
7. 10.1016/j.ensm.2021.10.03310.1016/j.ensm.2021.10.033 ↗
8. 10.1002/adfm.20210385010.1002/adfm.202103850 ↗
9. 10.1002/adma.20190367510.1002/adma.201903675 ↗
10. 10.1002/advs.20210030910.1002/advs.202100309 ↗
11. 10.1002/advs.20210261210.1002/advs.202102612 ↗
12. 10.1002/anie.20200184410.1002/anie.202001844 ↗
13. 10.1002/adma.20220218810.1002/adma.202202188 ↗
14. 10.1002/eom2.1219010.1002/eom2.12190 ↗
15. 10.1021/acs.nanolett.1c0391710.1021/acs.nanolett.1c03917 ↗
16. 10.1002/adfm.20190852810.1002/adfm.201908528 ↗
17. 10.1007/s40820-021-00599-210.1007/s40820-021-00599-2 ↗
18. 10.1002/adma.20200302110.1002/adma.202003021 ↗
19. 10.1021/acs.nanolett.1c0497510.1021/acs.nanolett.1c04975 ↗
20. 10.1038/s41565-021-00908-110.1038/s41565-021-00908-1 ↗
21. 10.1039/C9EE03545A10.1039/C9EE03545A ↗
22. 10.1016/j.cej.2021.13437810.1016/j.cej.2021.134378 ↗
23. 10.1016/j.cej.2022.14101510.1016/j.cej.2022.141015 ↗
24. 10.1038/srep0396510.1038/srep03965 ↗
25. Chen W. W. · China Petroleum Processing and Petrochemical Technology · 2018 · 20 · 56
26. 10.1039/C4NJ01396D10.1039/C4NJ01396D ↗
27. 10.1016/j.ensm.2020.04.03810.1016/j.ensm.2020.04.038 ↗
28. 10.1039/D0TA00748J10.1039/D0TA00748J ↗
29. 10.1002/aenm.20210098210.1002/aenm.202100982 ↗
30. 10.1016/j.joule.2021.12.00910.1016/j.joule.2021.12.009 ↗
31. 10.1039/C9EE00596J10.1039/C9EE00596J ↗
32. 10.1016/j.ensm.2021.10.01610.1016/j.ensm.2021.10.016 ↗
33. 10.1002/adma.20190034210.1002/adma.201900342 ↗
34. 10.1002/adfm.20210611410.1002/adfm.202106114 ↗
35. 10.31635/ccschem.021.20210125710.31635/ccschem.021.202101257 ↗
36. 10.1002/anie.20210575610.1002/anie.202105756 ↗
37. 10.1021/jacs.9b0502910.1021/jacs.9b05029 ↗
38. 10.31635/ccschem.019.2018001610.31635/ccschem.019.20180016 ↗
39. 10.1002/anie.20210968210.1002/anie.202109682 ↗
40. 10.1002/adma.20210513310.1002/adma.202105133 ↗
41. 10.31635/ccschem.021.20210121410.31635/ccschem.021.202101214 ↗
42. 10.1002/adfm.20210039810.1002/adfm.202100398 ↗
43. 10.1002/aenm.20180109010.1002/aenm.201801090 ↗