Morphological Reversibility of Modified Li-Based Anodes for Next-Generation Batteries
Source abstract
Abstract
Although a great variety of strategies to suppress Li dendrite have been proposed for lithium metal batteries (LMBs), a deeper understanding of the factors playing a crucial role during extended electrochemical cycling is often lacking. Herein, the morphological reversibility of the Li-based anode for next-generation batteries under three prevalent strategies, i.e., the use of Li–Al alloys, polymer coating, and anodic aluminum oxide (AAO) membrane attachment, has been sophisticatedly investigated by nondestructive visualization. The characterizations clearly capture the unprecedented morphological evolution of the Li-based anode during the electrochemical cycling. Furthermore, the results unambiguously indicate the formation of the “dead” electrochemically generated porous structures regardless of >99% cycling efficiency shown in Li symmetric cells in all three cell configurations. The results presented here shed light on further understanding of the morphological evolution of the Li anode under different scenarios, and it also enlightens us on new research activities that may assist in propelling the commercialization of LMBs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
Institute of Applied Materials, Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany
MEET Battery Research Center, University of Münster, Corrensstraße 46, D-48149 Münster, Germany
Helmholtz Institute Münster − Forschungszentrum Jülich GmbH (IEK 12), Corrensstraße 46, D-48149 Münster, Germany
Institute of Material Science and Technologies, Technical University Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany
State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China
Institute of Soft Matter and Functional Materials, Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany
Diamond Light Source Ltd., Harwell Science & Innovation Campus, Didcot, Oxfordshire OX11 0DE, United Kingdom
National Institute of Chemistry, Hajdrihova 19, SI-1001 Ljubljana, Slovenia
Funding
Deutsche Forschungsgemeinschaft · China Scholarship Council
References (83)
Show source-provided references
1. 10.1038/s41560-018-0107-210.1038/s41560-018-0107-2 ↗
2. 10.1021/acs.chemrev.8b0042210.1021/acs.chemrev.8b00422 ↗
3. 10.1007/s10800-013-0533-610.1007/s10800-013-0533-6 ↗
4. 10.1007/s10008-017-3610-710.1007/s10008-017-3610-7 ↗
5. 10.1039/C4CP05865H10.1039/C4CP05865H ↗
6. 10.1016/j.electacta.2013.01.02310.1016/j.electacta.2013.01.023 ↗
7. 10.1021/acs.nanolett.7b0360610.1021/acs.nanolett.7b03606 ↗
8. 10.1039/C8CC02280A10.1039/C8CC02280A ↗
9. 10.1016/j.nanoen.2016.12.00110.1016/j.nanoen.2016.12.001 ↗
10. 10.1016/j.joule.2017.11.00910.1016/j.joule.2017.11.009 ↗
11. 10.1016/S0378-7753(98)00242-010.1016/S0378-7753(98)00242-0 ↗
12. 10.1021/acsenergylett.8b0093510.1021/acsenergylett.8b00935 ↗
13. 10.1039/C8EE02601G10.1039/C8EE02601G ↗
14. 10.1039/C8TA00962G10.1039/C8TA00962G ↗
15. 10.1002/aenm.20190001910.1002/aenm.201900019 ↗
16. 10.1002/smll.20180373410.1002/smll.201803734 ↗
17. 10.1021/jacs.8b1048810.1021/jacs.8b10488 ↗
18. 10.1002/aenm.20180235010.1002/aenm.201802350 ↗
19. 10.1002/adfm.20140295310.1002/adfm.201402953 ↗
20. 10.1149/2.0401908jes10.1149/2.0401908jes ↗
21. 10.1524/zpch.2009.608610.1524/zpch.2009.6086 ↗
22. 10.1021/jp002526b10.1021/jp002526b ↗
23. 10.1038/s41565-018-0183-210.1038/s41565-018-0183-2 ↗
24. 10.1021/acs.chemmater.8b0072210.1021/acs.chemmater.8b00722 ↗
25. 10.1016/j.jpowsour.2018.08.07710.1016/j.jpowsour.2018.08.077 ↗
26. 10.1002/adma.20180468410.1002/adma.201804684 ↗
27. 10.1002/adma.20180778910.1002/adma.201807789 ↗
28. 10.1149/1.185085410.1149/1.1850854 ↗
29. 10.1149/2.030203jes10.1149/2.030203jes ↗
30. 10.1039/C8TA08095J10.1039/C8TA08095J ↗
31. 10.1021/acs.chemmater.7b0149610.1021/acs.chemmater.7b01496 ↗
32. 10.1016/j.joule.2018.05.00710.1016/j.joule.2018.05.007 ↗
33. 10.1002/smll.20170437110.1002/smll.201704371 ↗
34. 10.1126/science.aap878710.1126/science.aap8787 ↗
35. 10.1016/j.chempr.2018.06.01710.1016/j.chempr.2018.06.017 ↗
36. 10.1002/aenm.20180401910.1002/aenm.201804019 ↗
37. 10.1002/anie.20181195510.1002/anie.201811955 ↗
38. 10.1038/s41467-018-03466-810.1038/s41467-018-03466-8 ↗
39. 10.1021/acscentsci.6b0026010.1021/acscentsci.6b00260 ↗
40. 10.1002/cssc.20180196910.1002/cssc.201801969 ↗
41. 10.1002/cssc.20160022010.1002/cssc.201600220 ↗
42. 10.1016/j.mattod.2018.11.00310.1016/j.mattod.2018.11.003 ↗
43. 10.1021/acsenergylett.6b0058910.1021/acsenergylett.6b00589 ↗
44. 10.1021/acsenergylett.7b0125410.1021/acsenergylett.7b01254 ↗
45. 10.1021/acsenergylett.8b0224210.1021/acsenergylett.8b02242 ↗
46. 10.1021/acsnano.6b0393910.1021/acsnano.6b03939 ↗
47. 10.1002/aenm.20180317010.1002/aenm.201803170 ↗
48. 10.1039/C8EE00937F10.1039/C8EE00937F ↗
49. 10.1038/s41560-018-0096-110.1038/s41560-018-0096-1 ↗
50. 10.1002/admi.20170016610.1002/admi.201700166 ↗
51. 10.1016/j.apsusc.2016.12.09310.1016/j.apsusc.2016.12.093 ↗
52. 10.1021/nl034765r10.1021/nl034765r ↗
53. 10.5796/electrochemistry.82.36410.5796/electrochemistry.82.364 ↗
54. 10.1039/C7TA03116E10.1039/C7TA03116E ↗
55. 10.1039/C7EE03365F10.1039/C7EE03365F ↗
56. 10.1021/acsaem.8b0013210.1021/acsaem.8b00132 ↗
57. 10.1002/aenm.20130065410.1002/aenm.201300654 ↗
58. 10.1021/acsami.8b0339110.1021/acsami.8b03391 ↗
59. 10.1039/C6EE01674J10.1039/C6EE01674J ↗
60. 10.1016/j.joule.2018.08.01810.1016/j.joule.2018.08.018 ↗
61. 10.1016/0376-7388(94)00184-Z10.1016/0376-7388(94)00184-Z ↗
62. 10.1021/acsenergylett.6b0065010.1021/acsenergylett.6b00650 ↗
63. 10.1021/ja312241y10.1021/ja312241y ↗
64. 10.1002/celc.20180165210.1002/celc.201801652 ↗
65. 10.1038/ncomms736210.1038/ncomms7362 ↗
66. 10.1021/acsnano.7b0551310.1021/acsnano.7b05513 ↗
67. 10.1021/acsnano.5b0087610.1021/acsnano.5b00876 ↗
68. 10.1016/j.joule.2019.02.00410.1016/j.joule.2019.02.004 ↗
69. 10.1002/aenm.20190057410.1002/aenm.201900574 ↗
70. 10.1016/j.electacta.2016.02.10210.1016/j.electacta.2016.02.102 ↗
71. 10.1021/acsami.8b0873110.1021/acsami.8b08731 ↗
72. 10.1021/jacs.6b0873010.1021/jacs.6b08730 ↗
73. 10.1021/acsaem.8b0125610.1021/acsaem.8b01256 ↗
74. 10.1021/acsenergylett.8b0252710.1021/acsenergylett.8b02527 ↗
75. 10.1016/j.chempr.2018.05.00210.1016/j.chempr.2018.05.002 ↗
76. 10.1016/j.mattod.2018.08.00310.1016/j.mattod.2018.08.003 ↗
77. 10.1016/j.nanoen.2019.05.02210.1016/j.nanoen.2019.05.022 ↗
78. 10.1021/acs.nanolett.8b0314810.1021/acs.nanolett.8b03148 ↗
79. 10.1126/science.aam601410.1126/science.aam6014 ↗
80. 10.1016/j.joule.2018.08.00410.1016/j.joule.2018.08.004 ↗
81. 10.1038/s41586-018-0397-310.1038/s41586-018-0397-3 ↗
82. 10.1002/anie.20190010510.1002/anie.201900105 ↗
83. 10.1038/s41586-019-1481-z10.1038/s41586-019-1481-z ↗