journal article·2024-06-14

Working Principles of High-Entropy Electrolytes in Rechargeable Batteries

Ke-Feng Ren, He Liu, Jia-Xin Guo, Xin Sun, Feng Jiang, Cong Guo, Weizhai Bao, Feng Yu, Gulnur Kalimuldina, Long Kong, Xin-Bing Cheng, Jingfa Li

ACS Energy Letters· Volume 9· Issue 6
Publisher page

Abstract

Rechargeable batteries are considered to be one of the most feasible solutions to the energy crisis and environmental pollution. As a bridge between the cathode and the anode of the battery, electrolytes play critical roles in improving the battery performance. Recently, high-entropy electrolytes (HEEs) with unique properties were proposed. Specifically, HEEs can accelerate ionic diffusion kinetics and promote the dissolution of salts as well as broaden the operating temperature of batteries. This Review provides a comprehensive summary of the application and working mechanisms of HEEs in rechargeable batteries. First, the motivation, history, and definitions of HEEs are introduced. Then, the roles of HEEs in enhancing electrochemical performance in liquid and solid-state batteries are presented, especially in improving ionic conductivity and achieving a wide temperature range. Finally, the current issues and possible future directions of the HEEs are proposed. This Review provides a new perspective on the design of high-performance electrolytes.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Advanced Materials and Flexible Electronics (IAMFE), School of Chemistry and Materials Science, Nanjing University of Information Science and Technology, Nanjing 210044, Jiangsu, China

Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 211189, Jiangsu, China

Department of Mechanical and Aerospace Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Kabanbay Batyr Ave, 53, Astana 010000, Kazakhstan

Frontiers Science Center for Flexible Electronics and Xi’an Institute of Flexible Electronics, Northwestern Polytechnical University, Xi’an 710129, China

Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, Jiangsu, China

Funding

Startup Foundation for Introducing Talent of Nanjing University of Information Science and Technology · Natural Science Foundation of Jiangsu Province · Fundamental Research Funds for the Central Universities · National Natural Science Foundation of China · Jiangsu Specially Appointed Professor Program

References (100+)

Show source-provided references
1. 10.1038/s41560-019-0405-310.1038/s41560-019-0405-3 ↗
2. 10.1002/aenm.20210202810.1002/aenm.202102028 ↗
3. 10.1016/j.ensm.2019.09.02010.1016/j.ensm.2019.09.020 ↗
4. 10.1039/c2ee21892e10.1039/c2ee21892e ↗
5. 10.1002/adma.20230208610.1002/adma.202302086 ↗
6. 10.1016/j.mattod.2022.02.01310.1016/j.mattod.2022.02.013 ↗
7. 10.1002/smll.20220531510.1002/smll.202205315 ↗
8. 10.1016/j.mser.2018.07.00110.1016/j.mser.2018.07.001 ↗
9. 10.1021/acsenergylett.9b0144110.1021/acsenergylett.9b01441 ↗
10. 10.1016/j.jpowsour.2022.23220310.1016/j.jpowsour.2022.232203 ↗
11. 10.1557/mrs.2013.15210.1557/mrs.2013.152 ↗
12. 10.1016/j.ensm.2021.11.03310.1016/j.ensm.2021.11.033 ↗
13. 10.1038/s41560-019-0336-z10.1038/s41560-019-0336-z ↗
14. 10.1016/j.est.2021.10356410.1016/j.est.2021.103564 ↗
15. 10.1038/s41560-021-00783-z10.1038/s41560-021-00783-z ↗
16. 10.1002/eem2.1201210.1002/eem2.12012 ↗
17. 10.1021/acs.chemrev.9b0053110.1021/acs.chemrev.9b00531 ↗
18. 10.1021/acs.chemrev.3c0017410.1021/acs.chemrev.3c00174 ↗
19. 10.1016/j.ensm.2018.09.02410.1016/j.ensm.2018.09.024 ↗
20. 10.1021/acs.chemrev.0c0010110.1021/acs.chemrev.0c00101 ↗
21. 10.1039/D2TA07516D10.1039/D2TA07516D ↗
22. 10.1002/ese3.116310.1002/ese3.1163 ↗
23. 10.1016/j.est.2023.10671610.1016/j.est.2023.106716 ↗
24. 10.1038/s41467-023-36075-110.1038/s41467-023-36075-1 ↗
25. 10.1016/j.ensm.2022.06.00310.1016/j.ensm.2022.06.003 ↗
26. 10.1039/D3CS00151B10.1039/D3CS00151B ↗
27. 10.1016/j.nanoen.2022.10726510.1016/j.nanoen.2022.107265 ↗
28. 10.31635/ccschem.020.20200034110.31635/ccschem.020.202000341 ↗
29. 10.1016/j.nanoen.2018.10.03510.1016/j.nanoen.2018.10.035 ↗
30. 10.1039/D1EE00049G10.1039/D1EE00049G ↗
31. 10.1021/acsami.1c1258910.1021/acsami.1c12589 ↗
32. 10.1002/adma.20220940210.1002/adma.202209402 ↗
33. 10.1039/C6EE00123H10.1039/C6EE00123H ↗
34. 10.1021/acs.iecr.3c0220210.1021/acs.iecr.3c02202 ↗
35. 10.1002/sstr.20200012210.1002/sstr.202000122 ↗
36. 10.1016/j.etran.2022.10021110.1016/j.etran.2022.100211 ↗
37. 10.1021/acsenergylett.1c0105410.1021/acsenergylett.1c01054 ↗
38. 10.1002/adfm.20221135510.1002/adfm.202211355 ↗
39. 10.1002/adma.20230759910.1002/adma.202307599 ↗
40. 10.1002/adem.20030056710.1002/adem.200300567 ↗
41. 10.1038/ncomms948510.1038/ncomms9485 ↗
42. 10.1016/j.actamat.2020.07.00310.1016/j.actamat.2020.07.003 ↗
43. 10.1016/j.jechem.2020.12.02910.1016/j.jechem.2020.12.029 ↗
44. 10.1039/D1EE01543E10.1039/D1EE01543E ↗
45. 10.1016/j.cej.2021.13344810.1016/j.cej.2021.133448 ↗
46. 10.1038/s41467-018-05774-510.1038/s41467-018-05774-5 ↗
47. 10.1039/C9EE00368A10.1039/C9EE00368A ↗
48. 10.3390/met1305083310.3390/met13050833 ↗
49. 10.1002/anie.20191217110.1002/anie.201912171 ↗
50. 10.1038/s41563-020-00816-010.1038/s41563-020-00816-0 ↗
51. 10.1016/j.scriptamat.2021.11438710.1016/j.scriptamat.2021.114387 ↗
52. 10.1002/smll.20220674210.1002/smll.202206742 ↗
53. 10.1016/j.est.2023.10741910.1016/j.est.2023.107419 ↗
54. 10.1021/jacs.1c0900610.1021/jacs.1c09006 ↗
55. 10.1021/acsenergylett.2c0258510.1021/acsenergylett.2c02585 ↗
56. 10.1039/D2EE03682G10.1039/D2EE03682G ↗
57. 10.1126/science.abq134610.1126/science.abq1346 ↗
58. 10.3390/encyclopedia201001810.3390/encyclopedia2010018 ↗
59. 10.1016/j.actamat.2016.08.08110.1016/j.actamat.2016.08.081 ↗
60. 10.1016/j.apsusc.2018.12.30010.1016/j.apsusc.2018.12.300 ↗
61. 10.1039/D0TA09578H10.1039/D0TA09578H ↗
62. 10.1016/j.ceramint.2019.11.23910.1016/j.ceramint.2019.11.239 ↗
63. 10.1039/D3CC02214E10.1039/D3CC02214E ↗
64. 10.1038/s41893-022-01028-x10.1038/s41893-022-01028-x ↗
65. 10.1021/acsmaterialslett.2c0066710.1021/acsmaterialslett.2c00667 ↗
66. 10.1021/jacs.3c0427910.1021/jacs.3c04279 ↗
67. 10.1002/adma.20221067710.1002/adma.202210677 ↗
68. 10.1002/anie.20230441110.1002/anie.202304411 ↗
69. 10.1021/acsnano.3c0975910.1021/acsnano.3c09759 ↗
70. 10.1038/s41560-023-01280-110.1038/s41560-023-01280-1 ↗
71. 10.1038/s41578-024-00654-510.1038/s41578-024-00654-5 ↗
72. 10.1038/s41467-024-45309-910.1038/s41467-024-45309-9 ↗
73. 10.1039/D3EE03821A10.1039/D3EE03821A ↗
74. 10.1016/j.jallcom.2018.05.06710.1016/j.jallcom.2018.05.067 ↗
75. 10.1016/j.actamat.2013.01.04210.1016/j.actamat.2013.01.042 ↗
76. 10.3166/acsm.31.633-64810.3166/acsm.31.633-648 ↗
77. 10.1038/s41563-020-00816-010.1038/s41563-020-00816-0 ↗
78. 10.1021/acscatal.2c0277810.1021/acscatal.2c02778 ↗
79. 10.1016/j.jallcom.2022.16676810.1016/j.jallcom.2022.166768 ↗
80. 10.1016/j.ijplas.2020.10281910.1016/j.ijplas.2020.102819 ↗
81. 10.1142/S175882512150006X10.1142/S175882512150006X ↗
82. 10.1016/j.jallcom.2018.12.30010.1016/j.jallcom.2018.12.300 ↗
83. 10.1126/science.add713810.1126/science.add7138 ↗
84. 10.1002/adma.20230181710.1002/adma.202301817 ↗
85. 10.1038/s41467-024-45258-310.1038/s41467-024-45258-3 ↗
86. 10.1002/eom2.1226110.1002/eom2.12261 ↗
87. 10.1021/acs.chemrev.7b0011510.1021/acs.chemrev.7b00115 ↗
88. 10.1002/advs.20150021310.1002/advs.201500213 ↗
89. 10.1021/acsenergylett.1c0242510.1021/acsenergylett.1c02425 ↗
90. 10.1002/1521-3773(20011015)40:20<3783::AID-ANIE3783>3.0.CO;2-J10.1002/1521-3773(20011015)40:20<3783::AID-ANIE3783>3.0.CO;2-J ↗
91. 10.1002/adma.20220468110.1002/adma.202204681 ↗
92. 10.1038/s41467-018-06077-510.1038/s41467-018-06077-5 ↗
93. 10.1002/anie.20231819710.1002/anie.202318197 ↗
94. 10.1002/adfm.20210956810.1002/adfm.202109568 ↗
95. 10.1038/s41598-019-42766-x10.1038/s41598-019-42766-x ↗
96. 10.1063/1.505506410.1063/1.5055064 ↗
97. 10.1039/D1EE03292E10.1039/D1EE03292E ↗
98. 10.1002/adfm.20190988710.1002/adfm.201909887 ↗
99. 10.1016/j.joule.2020.06.01110.1016/j.joule.2020.06.011 ↗
100. 10.1021/acs.jpclett.5b0172710.1021/acs.jpclett.5b01727 ↗